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• W2295089117 endingPage "104301" @default.
• W2295089117 startingPage "104301" @default.
• W2295089117 abstract "A set of state-specific transition rates for each rovibrational level is generated for the O2(X(3)Σ(g)(-))-O(3)P system using the quasi-classical trajectory method at temperatures observed in hypersonic flows. A system of master equations describes the relaxation of the rovibrational ensemble to thermal equilibrium under ideal heat bath conditions at a constant translational temperature. Vibrational and rotational relaxation times, obtained from the average internal energies, exhibit a pattern inherent in a chemically reactive collisional pair. An intrinsic feature of the O3 molecular system with a large attractive potential is a weak temperature dependence of the rovibrational transition rates. For this reason, the quasi-steady vibrational and rotational temperatures experience a maximum at increasing translational temperature. The energy rate coefficients, that characterize the average loss of internal energy due to dissociation, quickly diminish at high temperatures, compared to other molecular systems." @default.
• W2295089117 created "2016-06-24" @default.
• W2295089117 creator A5029805261 @default.
• W2295089117 creator A5014593532 @default.
• W2295089117 date "2016-03-14" @default.
• W2295089117 modified "2023-10-12" @default.
• W2295089117 title "Rovibrational energy transfer and dissociation in O₂–O collisions" @default.
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• W2295089117 doi "https://doi.org/10.1063/1.4943114" @default.
• W2295089117 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26979687" @default.
• W2295089117 hasPublicationYear "2016" @default.
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