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• W2295235108 abstract "In bulk heterojunction (BHJ) organic photovoltaics, particularly those using small molecules, electron donor and/or electron acceptor materials form a distributed network in the photoactive layer where critical photo-physical processes occur. Extensive research has recently focused on the importance of sulfur atoms in the small molecules. Little is known about the three-dimensional orientation of these sulfur atom-containing molecules. Herein, we report on our research concerning the heterojunction textures of the crystalline molecular orientation of small compounds having sulfur-containing units in the side chains, specifically, compounds known as DR3TSBDT that contain the alkylthio group and DR3TBDTT that does not. The improved performance of the DR3TBDTT-based devices, particularly in the photocurrent and the fill factor, was attributed to the large population of donor compound crystallites with a favorable face-on orientation along the perpendicular direction. This orientation resulted in efficient charge transport and a reduction in charge recombination. These findings underscore the great potential of small-molecule solar cells and suggest that even higher efficiencies can be achieved through materials development and molecular orientation control." @default.
• W2295235108 created "2016-06-24" @default.
• W2295235108 creator A5042536147 @default.
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• W2295235108 date "2016-01-01" @default.
• W2295235108 modified "2023-09-26" @default.
• W2295235108 title "Following the nanostructural molecular orientation guidelines for sulfur versus thiophene units in small molecule photovoltaic cells" @default.
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• W2295235108 doi "https://doi.org/10.1039/c6nr00775a" @default.
• W2295235108 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26987868" @default.
• W2295235108 hasPublicationYear "2016" @default.
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