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- W2295293669 abstract "Abstract A titanium oxide supported double metal cyanide (TiO 2 ‐DMC) was found to be a highly active catalyst for the reaction of CO 2 with propylene oxide to polyethercarbonates, which are useful polymer building blocks for polyurethane applications. The catalyst was prepared by coprecipitation of potassium hexacyanocobaltate(III) and titanium(IV) ethoxide with an excess amount of ZnCl 2 under slightly acidic conditions. The TiO 2 ‐DMC catalyst provided excellent selectivity to the polymer (>97 %) and outstanding productivity (>500 g polymer /g catalyst ). The TiO 2 ‐support enhanced the Lewis acidity of the DMC catalyst, which facilitated activation of the epoxide and adjusted the binding strength of the polymer chain to the surface of the catalyst." @default.
- W2295293669 created "2016-06-24" @default.
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- W2295293669 date "2016-03-07" @default.
- W2295293669 modified "2023-10-02" @default.
- W2295293669 title "Nanoparticulate TiO <sub>2</sub> ‐Supported Double Metal Cyanide Catalyst for the Copolymerization of CO <sub>2</sub> with Propylene Oxide" @default.
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- W2295293669 doi "https://doi.org/10.1002/ejic.201501187" @default.
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