FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2295374607> ?p ?o ?g. }

• W2295374607 endingPage "3973" @default.
• W2295374607 startingPage "3970" @default.
• W2295374607 abstract "We report an air and water stable electride Y5Si3 and its catalytic activity for direct ammonia synthesis. It crystallizes in the Mn5Si3-type structure and confines 0.79/f.u. anionic electrons in the quasi-one-dimensional holes. These anionic electrons strongly hybridize with yttrium 4d electrons, giving rise to improved chemical stability. The ammonia synthesis rate using Ru(7.8 wt %)-loaded Y5Si3 was as high as 1.9 mmol/g/h under 0.1 MPa and at 400 °C with activation energy of ∼50 kJ/mol. Its strong electron-donating ability to Ru metal of Y5Si3 is considered to enhance nitrogen dissociation and reduce the activation energy of ammonia synthesis reaction. Catalytic activity was not suppressed even after Y5Si3, once dipped into water, was used as the catalyst promoter. These findings provide novel insights into the design of simple catalysts for ammonia synthesis." @default.
• W2295374607 created "2016-06-24" @default.
• W2295374607 creator A5007812423 @default.
• W2295374607 creator A5025007469 @default.
• W2295374607 creator A5037974511 @default.
• W2295374607 creator A5046600167 @default.
• W2295374607 creator A5047674545 @default.
• W2295374607 creator A5064627878 @default.
• W2295374607 creator A5079050204 @default.
• W2295374607 creator A5089789240 @default.
• W2295374607 date "2016-03-18" @default.
• W2295374607 modified "2023-10-16" @default.
• W2295374607 title "Water Durable Electride Y₅Si₃: Electronic Structure and Catalytic Activity for Ammonia Synthesis" @default.
• W2295374607 cites W1600135520 @default.
• W2295374607 cites W1965467985 @default.
• W2295374607 cites W1980072692 @default.
• W2295374607 cites W1981368803 @default.
• W2295374607 cites W1986746711 @default.
• W2295374607 cites W1992023766 @default.
• W2295374607 cites W2000576052 @default.
• W2295374607 cites W2006308503 @default.
• W2295374607 cites W2018357790 @default.
• W2295374607 cites W2024464227 @default.
• W2295374607 cites W2028056984 @default.
• W2295374607 cites W2043695984 @default.
• W2295374607 cites W2050710708 @default.
• W2295374607 cites W2052986375 @default.
• W2295374607 cites W2067676595 @default.
• W2295374607 cites W2079607738 @default.
• W2295374607 cites W2083222334 @default.
• W2295374607 cites W2086158219 @default.
• W2295374607 cites W2087365852 @default.
• W2295374607 cites W2091750259 @default.
• W2295374607 cites W2126163458 @default.
• W2295374607 cites W2139490622 @default.
• W2295374607 cites W2160692701 @default.
• W2295374607 cites W2188006409 @default.
• W2295374607 cites W2953194890 @default.
• W2295374607 cites W320883460 @default.
• W2295374607 doi "https://doi.org/10.1021/jacs.6b00124" @default.
• W2295374607 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26972257" @default.
• W2295374607 hasPublicationYear "2016" @default.
• W2295374607 type Work @default.
• W2295374607 sameAs 2295374607 @default.
• W2295374607 citedByCount "203" @default.
• W2295374607 countsByYear W22953746072016 @default.
• W2295374607 countsByYear W22953746072017 @default.
• W2295374607 countsByYear W22953746072018 @default.
• W2295374607 countsByYear W22953746072019 @default.
• W2295374607 countsByYear W22953746072020 @default.
• W2295374607 countsByYear W22953746072021 @default.
• W2295374607 countsByYear W22953746072022 @default.
• W2295374607 countsByYear W22953746072023 @default.
• W2295374607 crossrefType "journal-article" @default.
• W2295374607 hasAuthorship W2295374607A5007812423 @default.
• W2295374607 hasAuthorship W2295374607A5025007469 @default.
• W2295374607 hasAuthorship W2295374607A5037974511 @default.
• W2295374607 hasAuthorship W2295374607A5046600167 @default.
• W2295374607 hasAuthorship W2295374607A5047674545 @default.
• W2295374607 hasAuthorship W2295374607A5064627878 @default.
• W2295374607 hasAuthorship W2295374607A5079050204 @default.
• W2295374607 hasAuthorship W2295374607A5089789240 @default.
• W2295374607 hasConcept C102931765 @default.
• W2295374607 hasConcept C121332964 @default.
• W2295374607 hasConcept C147120987 @default.
• W2295374607 hasConcept C147789679 @default.
• W2295374607 hasConcept C161790260 @default.
• W2295374607 hasConcept C178790620 @default.
• W2295374607 hasConcept C179104552 @default.
• W2295374607 hasConcept C181258405 @default.
• W2295374607 hasConcept C185592680 @default.
• W2295374607 hasConcept C2776382133 @default.
• W2295374607 hasConcept C2779851234 @default.
• W2295374607 hasConcept C531131001 @default.
• W2295374607 hasConcept C544153396 @default.
• W2295374607 hasConcept C62520636 @default.
• W2295374607 hasConcept C95121573 @default.
• W2295374607 hasConceptScore W2295374607C102931765 @default.
• W2295374607 hasConceptScore W2295374607C121332964 @default.
• W2295374607 hasConceptScore W2295374607C147120987 @default.
• W2295374607 hasConceptScore W2295374607C147789679 @default.
• W2295374607 hasConceptScore W2295374607C161790260 @default.
• W2295374607 hasConceptScore W2295374607C178790620 @default.
• W2295374607 hasConceptScore W2295374607C179104552 @default.
• W2295374607 hasConceptScore W2295374607C181258405 @default.
• W2295374607 hasConceptScore W2295374607C185592680 @default.
• W2295374607 hasConceptScore W2295374607C2776382133 @default.
• W2295374607 hasConceptScore W2295374607C2779851234 @default.
• W2295374607 hasConceptScore W2295374607C531131001 @default.
• W2295374607 hasConceptScore W2295374607C544153396 @default.
• W2295374607 hasConceptScore W2295374607C62520636 @default.
• W2295374607 hasConceptScore W2295374607C95121573 @default.
• W2295374607 hasFunder F4320320912 @default.
• W2295374607 hasFunder F4320334789 @default.
• W2295374607 hasIssue "12" @default.
• W2295374607 hasLocation W22953746071 @default.
• W2295374607 hasLocation W22953746072 @default.
• W2295374607 hasOpenAccess W2295374607 @default.

• next