FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2295835501> ?p ?o ?g. }

• W2295835501 endingPage "1660" @default.
• W2295835501 startingPage "1652" @default.
• W2295835501 abstract "We report photoelectron spectra of cis-HONO(-) formed from an association reaction of OH(-) and NO in a pulsed, plasma-entrainment ion source. The experimental data are assigned to the cis-HONO(-) isomer, which is predicted to be the global minimum on the anion potential energy surface. We do not find evidence for a significant contribution from trans-HONO(-). Electron photodetachment of cis-HONO(-) with 1613, 1064, 532, 355, and 301 nm photons accesses the ground X̃ (1)A' (S0) and excited ã (3)A″ (T1) states of neutral HONO. The photoelectron spectrum resulting from detachment forming cis-HONO (S0) exhibits a long vibrational progression, dominated by overtones and combination bands involving the central O-N stretching and ONO bending vibrations. This indicates that there is a significant change in the central O-N bond length between cis-HONO(-) and cis-HONO (S0). The electron affinity (EA) of cis-HONO is determined to be 0.356(8) eV. We also report the dissociation energy (D0) of cis-HONO(-), forming OH(-) + NO, as 0.594(9) eV, which is a factor of 4 decrease in the central O-N bond strength compared to neutral cis-HONO. The T1 state of cis-HONO is shown to be ∼2.3 eV higher in energy than cis-HONO (S0). Electron photodetachment to form cis-HONO (T1) accesses a transition state along the HO-NO bond dissociation coordinate. The resulting photoelectron spectrum exhibits broad peaks spaced by the terminal N═O stretching frequency. Electronic structure calculations and photoelectron spectrum simulations reported here show very good agreement with the experimental data." @default.
• W2295835501 created "2016-06-24" @default.
• W2295835501 creator A5043516724 @default.
• W2295835501 creator A5046613137 @default.
• W2295835501 creator A5063139880 @default.
• W2295835501 creator A5070135255 @default.
• W2295835501 date "2016-03-08" @default.
• W2295835501 modified "2023-10-16" @default.
• W2295835501 title "Photoelectron Spectroscopy of <i>cis-</i>Nitrous Acid Anion (<i>cis-</i>HONO^–)" @default.
• W2295835501 cites W1588790017 @default.
• W2295835501 cites W1629102815 @default.
• W2295835501 cites W1966702069 @default.
• W2295835501 cites W1971308593 @default.
• W2295835501 cites W1975755123 @default.
• W2295835501 cites W1981063655 @default.
• W2295835501 cites W1985702861 @default.
• W2295835501 cites W1992015853 @default.
• W2295835501 cites W1996657809 @default.
• W2295835501 cites W1999447325 @default.
• W2295835501 cites W2000441335 @default.
• W2295835501 cites W2001083081 @default.
• W2295835501 cites W2006097842 @default.
• W2295835501 cites W2008007485 @default.
• W2295835501 cites W2011796905 @default.
• W2295835501 cites W2015062046 @default.
• W2295835501 cites W2015852426 @default.
• W2295835501 cites W2017125812 @default.
• W2295835501 cites W2021459723 @default.
• W2295835501 cites W2025211374 @default.
• W2295835501 cites W2030601571 @default.
• W2295835501 cites W2030854528 @default.
• W2295835501 cites W2033714604 @default.
• W2295835501 cites W2036357867 @default.
• W2295835501 cites W2039952005 @default.
• W2295835501 cites W2041335884 @default.
• W2295835501 cites W2042015604 @default.
• W2295835501 cites W2048648786 @default.
• W2295835501 cites W2066947044 @default.
• W2295835501 cites W2069799296 @default.
• W2295835501 cites W2070174862 @default.
• W2295835501 cites W2075323527 @default.
• W2295835501 cites W2076134521 @default.
• W2295835501 cites W2080684568 @default.
• W2295835501 cites W2081853548 @default.
• W2295835501 cites W2088147502 @default.
• W2295835501 cites W2088718795 @default.
• W2295835501 cites W2091593466 @default.
• W2295835501 cites W2095265958 @default.
• W2295835501 cites W2133345868 @default.
• W2295835501 cites W2142165370 @default.
• W2295835501 cites W2156481874 @default.
• W2295835501 cites W2160718521 @default.
• W2295835501 cites W2312459638 @default.
• W2295835501 cites W2582717733 @default.
• W2295835501 cites W3023936924 @default.
• W2295835501 doi "https://doi.org/10.1021/acs.jpca.5b11797" @default.
• W2295835501 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26886478" @default.
• W2295835501 hasPublicationYear "2016" @default.
• W2295835501 type Work @default.
• W2295835501 sameAs 2295835501 @default.
• W2295835501 citedByCount "7" @default.
• W2295835501 countsByYear W22958355012016 @default.
• W2295835501 countsByYear W22958355012018 @default.
• W2295835501 countsByYear W22958355012019 @default.
• W2295835501 countsByYear W22958355012022 @default.
• W2295835501 crossrefType "journal-article" @default.
• W2295835501 hasAuthorship W2295835501A5043516724 @default.
• W2295835501 hasAuthorship W2295835501A5046613137 @default.
• W2295835501 hasAuthorship W2295835501A5063139880 @default.
• W2295835501 hasAuthorship W2295835501A5070135255 @default.
• W2295835501 hasConcept C102931765 @default.
• W2295835501 hasConcept C121332964 @default.
• W2295835501 hasConcept C145148216 @default.
• W2295835501 hasConcept C147789679 @default.
• W2295835501 hasConcept C175708663 @default.
• W2295835501 hasConcept C178790620 @default.
• W2295835501 hasConcept C179104552 @default.
• W2295835501 hasConcept C181500209 @default.
• W2295835501 hasConcept C184779094 @default.
• W2295835501 hasConcept C185592680 @default.
• W2295835501 hasConcept C2776419827 @default.
• W2295835501 hasConcept C46141821 @default.
• W2295835501 hasConcept C51286037 @default.
• W2295835501 hasConcept C54582936 @default.
• W2295835501 hasConcept C75473681 @default.
• W2295835501 hasConceptScore W2295835501C102931765 @default.
• W2295835501 hasConceptScore W2295835501C121332964 @default.
• W2295835501 hasConceptScore W2295835501C145148216 @default.
• W2295835501 hasConceptScore W2295835501C147789679 @default.
• W2295835501 hasConceptScore W2295835501C175708663 @default.
• W2295835501 hasConceptScore W2295835501C178790620 @default.
• W2295835501 hasConceptScore W2295835501C179104552 @default.
• W2295835501 hasConceptScore W2295835501C181500209 @default.
• W2295835501 hasConceptScore W2295835501C184779094 @default.
• W2295835501 hasConceptScore W2295835501C185592680 @default.
• W2295835501 hasConceptScore W2295835501C2776419827 @default.
• W2295835501 hasConceptScore W2295835501C46141821 @default.
• W2295835501 hasConceptScore W2295835501C51286037 @default.

• next