FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2295859581> ?p ?o ?g. }

• W2295859581 endingPage "7737" @default.
• W2295859581 startingPage "7723" @default.
• W2295859581 abstract "The optical and morphological properties of lustrous metal self-healing liquid-like nanofilms were systematically studied for different applications (e.g., optical mirrors or filters). These nanofilms were formed by a one-step self-assembly methodology of gold nanoparticles (AuNPs) at immiscible water–oil interfaces, previously reported by our group. We investigated a host of experimental variables and herein report their influence on the optical properties of nanofilms: AuNP mean diameter, interfacial AuNP surface coverage, nature of the organic solvent, and nature of the lipophilic organic molecule that caps the AuNPs in the interfacial nanofilm. To probe the interfacial gold nanofilms we used in situ (UV-vis-NIR spectroscopy and optical microscopy) as well as ex situ (SEM and TEM of interfacial gold nanofilms transferred to silicon substrates) techniques. The interfacial AuNP surface coverage strongly influenced the morphology of the interfacial nanofilms, and in turn their maximum reflectance and absorbance. We observed three distinct morphological regimes; (i) smooth 2D monolayers of “floating islands” of AuNPs at low surface coverages, (ii) a mixed 2D/3D regime with the beginnings of 3D nanostructures consisting of small piles of adsorbed AuNPs even under sub-full-monolayer conditions and, finally, (iii) a 3D regime characterised by the 2D full-monolayer being covered in significant piles of adsorbed AuNPs. A maximal value of reflectance reached 58% in comparison with a solid gold mirror, when 38 nm mean diameter AuNPs were used at a water–nitrobenzene interface. Meanwhile, interfacial gold nanofilms prepared with 12 nm mean diameter AuNPs exhibited the highest extinction intensities at ca. 690 nm and absorbance around 90% of the incident light, making them an attractive candidate for filtering applications. Furthermore, the interparticle spacing, and resulting interparticle plasmon coupling derived optical properties, varied significantly on replacing tetrathiafulvalene with neocuproine as the AuNP capping ligand in the nanofilm. These interfacial nanofilms formed with neocuproine and 38 nm mean diameter AuNPs, at monolayer surface coverages and above, were black due to aggregation and broadband absorbance." @default.
• W2295859581 created "2016-06-24" @default.
• W2295859581 creator A5010061178 @default.
• W2295859581 creator A5014703396 @default.
• W2295859581 creator A5026713106 @default.
• W2295859581 creator A5073273835 @default.
• W2295859581 creator A5078676841 @default.
• W2295859581 date "2016-01-01" @default.
• W2295859581 modified "2023-09-30" @default.
• W2295859581 title "Self-healing gold mirrors and filters at liquid–liquid interfaces" @default.
• W2295859581 cites W1916181607 @default.
• W2295859581 cites W1944202587 @default.
• W2295859581 cites W1964028323 @default.
• W2295859581 cites W1966811889 @default.
• W2295859581 cites W1967788294 @default.
• W2295859581 cites W1973033352 @default.
• W2295859581 cites W1976659711 @default.
• W2295859581 cites W1978959012 @default.
• W2295859581 cites W1983554118 @default.
• W2295859581 cites W1990263762 @default.
• W2295859581 cites W1998756112 @default.
• W2295859581 cites W2003482893 @default.
• W2295859581 cites W2006924113 @default.
• W2295859581 cites W2012656424 @default.
• W2295859581 cites W2017302085 @default.
• W2295859581 cites W2017335011 @default.
• W2295859581 cites W2021857692 @default.
• W2295859581 cites W2023851906 @default.
• W2295859581 cites W2028673084 @default.
• W2295859581 cites W2030705634 @default.
• W2295859581 cites W2032230367 @default.
• W2295859581 cites W2036091087 @default.
• W2295859581 cites W2040852032 @default.
• W2295859581 cites W2044440155 @default.
• W2295859581 cites W2046890061 @default.
• W2295859581 cites W2051885876 @default.
• W2295859581 cites W2055824024 @default.
• W2295859581 cites W2056535274 @default.
• W2295859581 cites W2056891798 @default.
• W2295859581 cites W2061301950 @default.
• W2295859581 cites W2061335965 @default.
• W2295859581 cites W2063693442 @default.
• W2295859581 cites W2064235730 @default.
• W2295859581 cites W2064398870 @default.
• W2295859581 cites W2067854129 @default.
• W2295859581 cites W2068721104 @default.
• W2295859581 cites W2069224618 @default.
• W2295859581 cites W2073301204 @default.
• W2295859581 cites W2079037979 @default.
• W2295859581 cites W2079738594 @default.
• W2295859581 cites W2082782329 @default.
• W2295859581 cites W2083190112 @default.
• W2295859581 cites W2084588988 @default.
• W2295859581 cites W2086785431 @default.
• W2295859581 cites W2088299501 @default.
• W2295859581 cites W2092842745 @default.
• W2295859581 cites W2095098793 @default.
• W2295859581 cites W2099076026 @default.
• W2295859581 cites W2101035447 @default.
• W2295859581 cites W2107154212 @default.
• W2295859581 cites W2107765423 @default.
• W2295859581 cites W2109606219 @default.
• W2295859581 cites W2110357563 @default.
• W2295859581 cites W2110880313 @default.
• W2295859581 cites W2113684890 @default.
• W2295859581 cites W2113726949 @default.
• W2295859581 cites W2114808679 @default.
• W2295859581 cites W2115029038 @default.
• W2295859581 cites W2132905138 @default.
• W2295859581 cites W2134652845 @default.
• W2295859581 cites W2137864764 @default.
• W2295859581 cites W2138819172 @default.
• W2295859581 cites W2145687484 @default.
• W2295859581 cites W2156549570 @default.
• W2295859581 cites W2156641530 @default.
• W2295859581 cites W2158897252 @default.
• W2295859581 cites W2272695691 @default.
• W2295859581 cites W2285119349 @default.
• W2295859581 cites W2315043457 @default.
• W2295859581 cites W2315596724 @default.
• W2295859581 cites W2318650232 @default.
• W2295859581 cites W2318666785 @default.
• W2295859581 cites W2323632664 @default.
• W2295859581 cites W2326924422 @default.
• W2295859581 cites W2327794020 @default.
• W2295859581 cites W2331563982 @default.
• W2295859581 cites W2333908613 @default.
• W2295859581 cites W2335303813 @default.
• W2295859581 cites W2336156156 @default.
• W2295859581 cites W2339965549 @default.
• W2295859581 cites W2345076887 @default.
• W2295859581 cites W2484513983 @default.
• W2295859581 cites W4213235292 @default.
• W2295859581 cites W4241514575 @default.
• W2295859581 cites W2003567291 @default.
• W2295859581 doi "https://doi.org/10.1039/c6nr00371k" @default.
• W2295859581 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27001646" @default.
• W2295859581 hasPublicationYear "2016" @default.

• next