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• W2295882009 abstract "Solubility of β-diketone (4-ethyl-1-phenyl-1, 3-octadione, abbreviated as HA, C16H22O2, molecular weight, 246.34)–ZnSO4–(NH4)2SO4–NH3(aq)–H2O system at T = (298.15, 308.15) K is elaborately measured by isothermal method. The results show that the solubility of ZnA2(o), NH4A(o), H2O(o), Zn2+(w), NH4+(w), SO42–(w), and HA(w) increases with the increase of the concentration of zinc sulfate. In contrast, the solubility of HA(o), H2O(w), and NH3(w) decreases with the increase of the concentration of zinc sulfate. The distribution ratio and extraction equilibrium isotherm of zinc in extraction system are obtained at T = (298.15, 308.15) K. The consequence indicates that extraction equilibrium isotherm is connected with temperature, and at the same condition, the distribution ratio of Zn(II) at 298.15 K is greater than 308.15 K. The activity coefficient of the components in mixture electrolyte solutions is calculated by Pitzer model, and the activity coefficient in organic phase is gained by correlating the extr..." @default.
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• W2295882009 date "2016-03-11" @default.
• W2295882009 modified "2023-09-25" @default.
• W2295882009 title "Thermodynamic Properties of the β-Diketone–ZnSO4–(NH4)2SO4–NH3(aq)–H2O System" @default.
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• W2295882009 doi "https://doi.org/10.1021/acs.jced.5b00969" @default.
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