Matches in SemOpenAlex for { <https://semopenalex.org/work/W2296155370> ?p ?o ?g. }
- W2296155370 endingPage "2071" @default.
- W2296155370 startingPage "2063" @default.
- W2296155370 abstract "Abstract Synthetic nickelian malachite nanopowders (Cu 1– x Ni x ) 2 (OH) 2 CO 3 with x = 0, 0.02, 0.04, 0.06, 0.08, and 0.1 were prepared by constant‐pH coprecipitation. N 2 sorption isotherms confirmed a steady increase of the BET surface area with increasing Ni content for the as‐synthesized and calcined mesoporous materials. Powder XRD patterns for x ≤ 0.1 indicate the formation of single‐phase materials with an anisotropic contraction of the unit cell. This is related to the gradual decrease of the Jahn–Teller distortion in the malachite structure. An XRD‐amorphous hydroxide‐rich phase is formed for x > 0.1, which appears as spongelike regions in SEM images. Thermogravimetric analysis showed that nickel lowers the onset of thermal decomposition. Powder XRD patterns of the calcined samples evidence the formation of a tenorite structure despite the presence of Ni. Heterogeneous Fenton‐like decomposition of Bismarck Brown Y with H 2 O 2 showed that a Cu/Ni ratio of 92:8 in the nanostructured oxide leads to the highest reaction rate constant derived from a pseudo‐first‐order kinetic rate law expression. Temperature‐programmed CO oxidation experiments revealed that pure CuO achieved the highest activity. Similar performance was observed for the binary system obtained through calcination of the precursor prepared with a Cu/Ni ratio of 96:4." @default.
- W2296155370 created "2016-06-24" @default.
- W2296155370 creator A5000126422 @default.
- W2296155370 creator A5015713832 @default.
- W2296155370 creator A5059822420 @default.
- W2296155370 creator A5066213817 @default.
- W2296155370 date "2016-03-10" @default.
- W2296155370 modified "2023-09-27" @default.
- W2296155370 title "Effect of Ni Incorporation into Malachite Precursors on the Catalytic Properties of the Resulting Nanostructured CuO/NiO Catalysts" @default.
- W2296155370 cites W1025517706 @default.
- W2296155370 cites W1964909514 @default.
- W2296155370 cites W1970615526 @default.
- W2296155370 cites W1980701169 @default.
- W2296155370 cites W1991103399 @default.
- W2296155370 cites W2003521312 @default.
- W2296155370 cites W2013065070 @default.
- W2296155370 cites W2013504490 @default.
- W2296155370 cites W2013606637 @default.
- W2296155370 cites W2015396336 @default.
- W2296155370 cites W2018268301 @default.
- W2296155370 cites W2022258254 @default.
- W2296155370 cites W2026222823 @default.
- W2296155370 cites W2026539378 @default.
- W2296155370 cites W2031724454 @default.
- W2296155370 cites W2038475522 @default.
- W2296155370 cites W2039432834 @default.
- W2296155370 cites W2044237191 @default.
- W2296155370 cites W2045885909 @default.
- W2296155370 cites W2047946709 @default.
- W2296155370 cites W2051788559 @default.
- W2296155370 cites W2058226315 @default.
- W2296155370 cites W2061538530 @default.
- W2296155370 cites W2073379707 @default.
- W2296155370 cites W2076221132 @default.
- W2296155370 cites W2077398270 @default.
- W2296155370 cites W2078446329 @default.
- W2296155370 cites W2094738456 @default.
- W2296155370 cites W2105998361 @default.
- W2296155370 cites W2115548629 @default.
- W2296155370 cites W2150857061 @default.
- W2296155370 doi "https://doi.org/10.1002/ejic.201501425" @default.
- W2296155370 hasPublicationYear "2016" @default.
- W2296155370 type Work @default.
- W2296155370 sameAs 2296155370 @default.
- W2296155370 citedByCount "7" @default.
- W2296155370 countsByYear W22961553702016 @default.
- W2296155370 countsByYear W22961553702017 @default.
- W2296155370 countsByYear W22961553702018 @default.
- W2296155370 countsByYear W22961553702019 @default.
- W2296155370 countsByYear W22961553702020 @default.
- W2296155370 countsByYear W22961553702021 @default.
- W2296155370 crossrefType "journal-article" @default.
- W2296155370 hasAuthorship W2296155370A5000126422 @default.
- W2296155370 hasAuthorship W2296155370A5015713832 @default.
- W2296155370 hasAuthorship W2296155370A5059822420 @default.
- W2296155370 hasAuthorship W2296155370A5066213817 @default.
- W2296155370 hasConcept C121332964 @default.
- W2296155370 hasConcept C13965031 @default.
- W2296155370 hasConcept C148898269 @default.
- W2296155370 hasConcept C160434732 @default.
- W2296155370 hasConcept C161790260 @default.
- W2296155370 hasConcept C178790620 @default.
- W2296155370 hasConcept C179104552 @default.
- W2296155370 hasConcept C185592680 @default.
- W2296155370 hasConcept C2777840564 @default.
- W2296155370 hasConcept C28737856 @default.
- W2296155370 hasConcept C544778455 @default.
- W2296155370 hasConcept C60100273 @default.
- W2296155370 hasConcept C62520636 @default.
- W2296155370 hasConcept C7082614 @default.
- W2296155370 hasConcept C74575197 @default.
- W2296155370 hasConcept C82776694 @default.
- W2296155370 hasConcept C93391505 @default.
- W2296155370 hasConceptScore W2296155370C121332964 @default.
- W2296155370 hasConceptScore W2296155370C13965031 @default.
- W2296155370 hasConceptScore W2296155370C148898269 @default.
- W2296155370 hasConceptScore W2296155370C160434732 @default.
- W2296155370 hasConceptScore W2296155370C161790260 @default.
- W2296155370 hasConceptScore W2296155370C178790620 @default.
- W2296155370 hasConceptScore W2296155370C179104552 @default.
- W2296155370 hasConceptScore W2296155370C185592680 @default.
- W2296155370 hasConceptScore W2296155370C2777840564 @default.
- W2296155370 hasConceptScore W2296155370C28737856 @default.
- W2296155370 hasConceptScore W2296155370C544778455 @default.
- W2296155370 hasConceptScore W2296155370C60100273 @default.
- W2296155370 hasConceptScore W2296155370C62520636 @default.
- W2296155370 hasConceptScore W2296155370C7082614 @default.
- W2296155370 hasConceptScore W2296155370C74575197 @default.
- W2296155370 hasConceptScore W2296155370C82776694 @default.
- W2296155370 hasConceptScore W2296155370C93391505 @default.
- W2296155370 hasIssue "13-14" @default.
- W2296155370 hasLocation W22961553701 @default.
- W2296155370 hasOpenAccess W2296155370 @default.
- W2296155370 hasPrimaryLocation W22961553701 @default.
- W2296155370 hasRelatedWork W1975424802 @default.
- W2296155370 hasRelatedWork W2029240758 @default.
- W2296155370 hasRelatedWork W2052352729 @default.
- W2296155370 hasRelatedWork W2075525936 @default.