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• W2296175082 abstract "Herein, we report a Zn-ProPhenol catalyzed Mannich reaction using α-branched ketones as nucleophilic partners for the direct enantio- and diastereoselective construction of quaternary carbon stereocenters. The reaction can be run on a gram-scale with a low catalyst loading without impacting its efficiency. Moreover, the Mannich adducts can be further elaborated with complete diastereocontrol to access molecules possessing complex stereotriads." @default.
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• W2296175082 date "2016-03-09" @default.
• W2296175082 modified "2023-10-11" @default.
• W2296175082 title "Direct Catalytic Asymmetric Mannich Reactions for the Construction of Quaternary Carbon Stereocenters" @default.
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• W2296175082 doi "https://doi.org/10.1021/jacs.6b01187" @default.
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