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• W2296355803 abstract "Today's olefin metathesis catalysts show high reactivity, selectivity, and functional group tolerance and allow the design of new syntheses of precisely functionalized polymers. Here the synthesis of a new end-capping reagent is investigated allowing the introduction of a highly reactive activated ester end-group at the polymer chain end as well as its prefunctionalization to directly introduce functional moieties. The versatility of this new end-capping reagent is demonstrated by utilizing it to synthesize a so-called termimer (a monomer with termination capabilities). Copolymerization of a norbornene derivative with the termimer leads to hyperbranched ring-opening metathesis polymerization polymers as proven by gel permeation chromatography and MALDI-ToF-(matrix-assisted laser desorption/ionization time of flight) mass spectrometry." @default.
• W2296355803 created "2016-06-24" @default.
• W2296355803 creator A5064638844 @default.
• W2296355803 creator A5074824440 @default.
• W2296355803 date "2016-01-20" @default.
• W2296355803 modified "2023-10-16" @default.
• W2296355803 title "Branched Polymers via ROMP of Termimers" @default.
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• W2296355803 doi "https://doi.org/10.1002/marc.201500628" @default.
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