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• W2296424811 abstract "AbstractIn this study, novel ferrocene-functionalized N-alkyl substituted pyrrole derivatives, namely 4-ferrocenyl-1-[3-(pyrrol-1-yl)propyl]-1H-1,2,3-triazole (Py3Fc), 4-ferrocenyl-1-[4-(pyrrol-1-yl)butyl]-1H-1,2,3-triazole (Py4Fc), and 4-ferrocenyl-1-[6-(pyrrol-1-yl)hexyl]-1H-1,2,3-triazole (Py6Fc), were synthesized via click reaction and the monomers were characterized by 1H NMR, 13C NMR, FTIR, and HRMS techniques. Redox properties of the monomers were investigated by cyclic voltammetry (CV) studies. Contrary to general literature, both Py4Fc and Py6Fc were electrochemically polymerized without loss in redox activity of ferrocene group. Moreover, click chemistry was utilized in post-polymerization functionalization. For this purpose, three azide-containing polypyrroles, P(Py3N3), P(Py4N3), and P(Py6N3) were electrochemically synthesized and subjected to click reaction in the presence of ethynylferrocene. CV studies of the post-polymerization functionalized polymers revealed quasi-reversible waves, while..." @default.
• W2296424811 created "2016-06-24" @default.
• W2296424811 creator A5051703977 @default.
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• W2296424811 date "2016-02-12" @default.
• W2296424811 modified "2023-09-23" @default.
• W2296424811 title "Ferrocene clicked polypyrrole derivatives: effect of spacer group on electrochemical properties and post-polymerization functionalization" @default.
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• W2296424811 doi "https://doi.org/10.1080/15685551.2015.1136526" @default.
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