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- W2297050633 abstract "A novel method for Pd-catalyzed triflination of aryl and heteroaryl triflates using NaSO2CF3 as the nucleophile is described. The combination of Pd2(dba)3 and RockPhos formed the most effective catalyst. A broad range of functional groups and heteroaromatic compounds were tolerated under the neutral reaction conditions. The order of reactivity ArOTf ≥ ArCl ≥ ArBr is consistent with transmetalation being a slow step of the reaction." @default.
- W2297050633 created "2016-06-24" @default.
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- W2297050633 date "2016-01-21" @default.
- W2297050633 modified "2023-09-29" @default.
- W2297050633 title "Pd-Catalyzed Synthesis of Aryl and Heteroaryl Triflones from Reactions of Sodium Triflinate with Aryl (Heteroaryl) Triflates" @default.
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- W2297050633 doi "https://doi.org/10.1021/acs.joc.5b02523" @default.
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