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• W2297266965 abstract "High-yielding one-pot production of glucose from cellulose has been achieved using an alkali-activated carbon K26 as a catalyst bearing weak acid sites. The hydrolysis of solid cellulose by solid catalyst is limited due to low physical contact between the substrate and catalyst, but a new ball-milling pretreatment, ball-milling cellulose and carbon together (named mix-milling), has drastically improved the hydrolysis rate. As a result, 90 % yield and 97 % selectivity of water-soluble glucans have been obtained by K26 at 453 K for 20 min. Model reactions and kinetic studies have shown that the mix-milling pretreatment selectively accelerates solid-solid reaction (cellulose to water-soluble oligosaccharides), but does not liquid-solid reaction (soluble oligosaccharides to glucose). Hence, a trace amount of HCl (0.012 wt%) is used to depolymerize oligosaccharides to glucose and as high as 88 % yield of glucose with 90 % selectivity has been achieved. This reaction system is also effective for the hydrolysis of cellulose/hemicellulose in bagasse kraft pulp to hexoses/pentoses." @default.
• W2297266965 created "2016-06-24" @default.
• W2297266965 creator A5001517975 @default.
• W2297266965 date "2016-01-01" @default.
• W2297266965 modified "2023-09-27" @default.
• W2297266965 title "Hydrolysis of Cellulose to Glucose Using Carbon Catalysts" @default.
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• W2297266965 doi "https://doi.org/10.1007/978-981-10-0332-5_2" @default.
• W2297266965 hasPublicationYear "2016" @default.
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