FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2297679964> ?p ?o ?g. }

• W2297679964 endingPage "25597" @default.
• W2297679964 startingPage "25591" @default.
• W2297679964 abstract "Thermally activated delayed fluorescence (TADF) is becoming an increasingly important OLED technology that extracts light from nonemissive triplet states via reverse intersystem crossing (RISC) to the bright singlet state. Here we present the rather surprising finding that in TADF materials that contain a mixture of donor and acceptor molecules the electron–hole separation fluctuates as a function of time. By performing time-resolved photoluminescence experiments, both with and without a magnetic field, we observe that at short times the TADF dynamics are insensitive to magnetic field, but a large magnetic field effect (MFE) occurs at longer times. We explain these observations by constructing a quantum mechanical rate model in which the electron and hole cycle between a near-neighbor exciplex state that shows no MFE and a separated polaron-pair state that is not emissive but does show magnetic field dependent dynamics. Interestingly, the model suggests that only a portion of TADF in these blends comes from direct RISC from triplet to singlet exciplex. A substantial contribution comes from an indirect path, where the electron and hole separate, undergo RISC from hyperfine interactions, and then recombine to form a bright singlet exciplex. These observations have a significant impact on the design rules for TADF materials, as they imply a separate set of electronic parameters that can influence efficiency." @default.
• W2297679964 created "2016-06-24" @default.
• W2297679964 creator A5005289180 @default.
• W2297679964 creator A5006511850 @default.
• W2297679964 creator A5012778333 @default.
• W2297679964 creator A5058619997 @default.
• W2297679964 creator A5064878604 @default.
• W2297679964 creator A5068974466 @default.
• W2297679964 date "2015-10-29" @default.
• W2297679964 modified "2023-10-18" @default.
• W2297679964 title "The Role of Electron–Hole Separation in Thermally Activated Delayed Fluorescence in Donor–Acceptor Blends" @default.
• W2297679964 cites W1753667521 @default.
• W2297679964 cites W1965215812 @default.
• W2297679964 cites W1966957194 @default.
• W2297679964 cites W1978301565 @default.
• W2297679964 cites W1981045930 @default.
• W2297679964 cites W1989440615 @default.
• W2297679964 cites W1990994326 @default.
• W2297679964 cites W1997365597 @default.
• W2297679964 cites W2005259257 @default.
• W2297679964 cites W2014548333 @default.
• W2297679964 cites W2015683881 @default.
• W2297679964 cites W2017066071 @default.
• W2297679964 cites W2017484561 @default.
• W2297679964 cites W2017908410 @default.
• W2297679964 cites W2018941284 @default.
• W2297679964 cites W2030537511 @default.
• W2297679964 cites W2031266633 @default.
• W2297679964 cites W2035586701 @default.
• W2297679964 cites W2037527248 @default.
• W2297679964 cites W2042631320 @default.
• W2297679964 cites W2046850272 @default.
• W2297679964 cites W2047343131 @default.
• W2297679964 cites W2047389938 @default.
• W2297679964 cites W2051293602 @default.
• W2297679964 cites W2052776225 @default.
• W2297679964 cites W2059027738 @default.
• W2297679964 cites W2061148175 @default.
• W2297679964 cites W2063646240 @default.
• W2297679964 cites W2065240690 @default.
• W2297679964 cites W2068449200 @default.
• W2297679964 cites W2068539433 @default.
• W2297679964 cites W2077046343 @default.
• W2297679964 cites W2078182162 @default.
• W2297679964 cites W2092919478 @default.
• W2297679964 cites W2097292371 @default.
• W2297679964 cites W2111038221 @default.
• W2297679964 cites W2113607315 @default.
• W2297679964 cites W2125072689 @default.
• W2297679964 cites W2150702843 @default.
• W2297679964 cites W2150810007 @default.
• W2297679964 cites W2156049208 @default.
• W2297679964 cites W2159999051 @default.
• W2297679964 cites W2313458881 @default.
• W2297679964 cites W2313934402 @default.
• W2297679964 cites W2332360247 @default.
• W2297679964 cites W2878404963 @default.
• W2297679964 cites W2949661855 @default.
• W2297679964 cites W4256172841 @default.
• W2297679964 doi "https://doi.org/10.1021/acs.jpcc.5b07340" @default.
• W2297679964 hasPublicationYear "2015" @default.
• W2297679964 type Work @default.
• W2297679964 sameAs 2297679964 @default.
• W2297679964 citedByCount "46" @default.
• W2297679964 countsByYear W22976799642016 @default.
• W2297679964 countsByYear W22976799642017 @default.
• W2297679964 countsByYear W22976799642018 @default.
• W2297679964 countsByYear W22976799642019 @default.
• W2297679964 countsByYear W22976799642020 @default.
• W2297679964 countsByYear W22976799642021 @default.
• W2297679964 countsByYear W22976799642022 @default.
• W2297679964 countsByYear W22976799642023 @default.
• W2297679964 crossrefType "journal-article" @default.
• W2297679964 hasAuthorship W2297679964A5005289180 @default.
• W2297679964 hasAuthorship W2297679964A5006511850 @default.
• W2297679964 hasAuthorship W2297679964A5012778333 @default.
• W2297679964 hasAuthorship W2297679964A5058619997 @default.
• W2297679964 hasAuthorship W2297679964A5064878604 @default.
• W2297679964 hasAuthorship W2297679964A5068974466 @default.
• W2297679964 hasConcept C115260700 @default.
• W2297679964 hasConcept C120665830 @default.
• W2297679964 hasConcept C121332964 @default.
• W2297679964 hasConcept C147120987 @default.
• W2297679964 hasConcept C159467904 @default.
• W2297679964 hasConcept C17729963 @default.
• W2297679964 hasConcept C181500209 @default.
• W2297679964 hasConcept C184779094 @default.
• W2297679964 hasConcept C185592680 @default.
• W2297679964 hasConcept C192562407 @default.
• W2297679964 hasConcept C26873012 @default.
• W2297679964 hasConcept C2779892579 @default.
• W2297679964 hasConcept C33062035 @default.
• W2297679964 hasConcept C49040817 @default.
• W2297679964 hasConcept C62520636 @default.
• W2297679964 hasConcept C73978554 @default.
• W2297679964 hasConcept C74561354 @default.
• W2297679964 hasConcept C75473681 @default.
• W2297679964 hasConcept C76766466 @default.

• next