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- W2297788126 abstract "Abstract. Two cadmium(II) coordination polymers, {CdL2[(CH3)2NH2]2·2DMF}n (1) and {[Cd3L4[(CH3)2NH2]2]·EtOH·2DMF}n (2) were synthesized from the solvothermal reactions of Cd(OAc)2·2H2O with 3,3′-(diazenediyl)dibenzoic acid (H2L) in different solvents. Both complexes were characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction, TG analysis, and single-crystal X-ray diffraction. In compound 1, central cadmium(II) atoms were linked with the surrounding L ligands to generate an infinite 1D chain with repeated rings. Compound 2 displayed a 3D threefold interpenetrating framework based on cage-like [Cd3L6]8 species and exhibited a 41263 topological structure. The results demonstrated that the different solvents had significant effect on the construction of different coordination compounds from the same components. In addition, they exhibited excellent stability and good photocatalytic activity towards the degradation of methylene blue in aqueous solution under UV irradiation." @default.
- W2297788126 created "2016-06-24" @default.
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- W2297788126 date "2016-01-29" @default.
- W2297788126 modified "2023-10-12" @default.
- W2297788126 title "Solvent Effect on the Assembly of Two Cadmium(II) Coordination Polymers Derived from 3,3′-(Diazenediyl)dibenzoic Acid: Syntheses, Structures, Stabilities, and Photocatalytic Properties" @default.
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- W2297788126 doi "https://doi.org/10.1002/zaac.201500705" @default.
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