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- W2298059668 abstract "A novel copper (II) coordination compound, [Cu(C9H6 O4)(C12H8N2)]. 4H2O (I), (3-carboxyl-5-methyl-salicylaldehyde anion)(phen)copper (II) tetrahydrate, was obtained. The authors present the synthesis method, crystal structure, and the intriguing water chains of (I). The compound is crystallized in triclinic system with space group P–1 and with the cell parameters: a = 6.9507(18) A, b = 11.025(3) A, c = 15.142(5) A, α = 107.617(4)°, β = 95.344(5)°, γ = 103.472(3)°; V = 1058.6(5) A3, Z = 2, Dc = 1.550 g/cm3, F(000) = 510, μ = 1.083 mm–1, S = 1.030, R = 0.0365, and wR = 0.0951 for 3273 observed reflections [I > 2σ(I)], Mr = 493.95. The coordination geometry around Cu(II) is a slightly distorted square planar with four-coordinated by two oxygen and two N atoms from the ligands. The two types of water rings (tetramembered water rings and hexamembered water rings), which share the same sides, are alternately created and interconnected to form an interesting 1-D water chain like the DNA molecular structure propa..." @default.
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- W2298059668 date "2013-10-21" @default.
- W2298059668 modified "2023-09-24" @default.
- W2298059668 title "Water Chains in a Novel Copper(II) Compound [Cu(C9H6O4)(C12H8N2)]. 4H2O" @default.
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- W2298059668 doi "https://doi.org/10.1080/15533174.2013.770023" @default.
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