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• W2298266909 endingPage "874" @default.
• W2298266909 startingPage "866" @default.
• W2298266909 abstract "A series of heterobimetallic Zr–Al complexes, [ZrCl{(O-2,4-tBu2C6H2-6-CH2)3(μ2-O-2,4-tBu2-C6H2-6-CH2)}N][R2Al(μ2-OiPr)] [R = Me (3), Et (4)] and [ZrR{(O-2,4-tBu2C6H2-6-CH2)3(μ2-O-2,4-tBu2-C6H2-6-CH2)}N][R2Al(μ2-OiPr)] [R = Et (5), iBu (6)], have been prepared by reactions of Zr(OiPr)[(O-2,4-tBu2C6H2-6-CH2)3N] (1) with 1.0 equiv of Al alkyls (Me2AlCl, Et2AlCl, AlEt3, and AliBu3), and their structures (3, 5, 6) were determined by X-ray crystallography. The isobutyl complex (6) is stable in C6D6 and toluene-d6 at 45 °C; the thermolysis of 6 at >60 °C gradually afforded 1 with liberation of AliBu3. These complexes exhibited remarkable catalytic activities for ethylene polymerization at 80–120 °C in the presence of MAO; only complex 6 exhibited the high activity even at 45–60 °C." @default.
• W2298266909 created "2016-06-24" @default.
• W2298266909 creator A5001837017 @default.
• W2298266909 creator A5008381633 @default.
• W2298266909 creator A5048382701 @default.
• W2298266909 date "2016-03-15" @default.
• W2298266909 modified "2023-10-03" @default.
• W2298266909 title "Synthesis and Structural Analysis of Zr–Al Heterobimetallic Complexes, [ZrX{(O-2,4-^<i>t</i>Bu₂C₆H₂-6-CH₂)₃(μ₂-O-2,4-^<i>t</i>Bu₂-C₆H₂-6-CH₂)}N][R₂Al(μ₂-O^<i>i</i>Pr)] [X = Cl, Et, ^<i>i</i>Bu; R = Me, Et, ^<i>i</i>Bu]. Unique Reactivity of the ^<i>i</i>Bu Complex" @default.
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• W2298266909 doi "https://doi.org/10.1021/acs.organomet.5b01027" @default.
• W2298266909 hasPublicationYear "2016" @default.
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