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- W2298633963 abstract "Single phase BaCe0.8Pr0.2O3−δ perovkite was obtained by the modified Pechini method followed by self-combustion and sintering at 1350°C. Crystal structure, thermodynamic stability, linear expansion and electrical properties were characterized as a function of temperature, under oxidizing and reducing atmospheres. BaCe0.8Pr0.2O3−δ presents phase transitions under both atmospheres, which do not compromise the transport properties. The electrical conductivity showed a mixed character, dominated by electronic and oxygen vacancies transport in O2-containing atmosphere. Pr+4 reduction was observed above 400°C under H2-containing atmosphere. This reduction increases the oxygen non-stoichiometry and OH• charge carriers concentration, unit cell volume and thermal expansion coefficients (TECs). Pr+4 reduction suppresses the electronic conduction and hence the transport number for OH• would be dominant in wet reducing atmosphere." @default.
- W2298633963 created "2016-06-24" @default.
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- W2298633963 date "2016-01-01" @default.
- W2298633963 modified "2023-10-17" @default.
- W2298633963 title "A High Temperature Study on the Structure, Linear Expansion, Thermodynamic Stability and Electrical Properties of the BaCe<sub>0.8</sub>Pr<sub>0.2</sub>O<sub>3−δ</sub>Perovskite" @default.
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- W2298633963 doi "https://doi.org/10.1149/2.0911606jes" @default.
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