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• W2298942080 endingPage "1614" @default.
• W2298942080 startingPage "1608" @default.
• W2298942080 abstract "Abstract The ability of several pnicogen sp 3 derivatives ZF 3 (Z=N, P, As, Sb) to interact with electron‐rich entities by means of the opposite face to the lone pair (lp) is investigated at the RI‐MP2/aug‐cc‐pVQZ level of theory. The strength of the interaction ranges from −1 to −87 kJ mol −1 , proving its favorable nature, especially when the lp is coordinated to a metal center, whereby the strength of the interaction is significantly enhanced. NBO analysis showed that orbital effects are modest contributors to the global stabilization of the pnicogen σ‐hole bonded complexes studied. Finally, a selection of Cambridge Structural Database examples are shown that demonstrate the impact of this counterintuitive binding mode in the solid state." @default.
• W2298942080 created "2016-06-24" @default.
• W2298942080 creator A5013755617 @default.
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• W2298942080 date "2016-03-23" @default.
• W2298942080 modified "2023-10-16" @default.
• W2298942080 title "σ-Hole Opposite to a Lone Pair: Unconventional Pnicogen Bonding Interactions between ZF₃(Z=N, P, As, and Sb) Compounds and Several Donors" @default.
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• W2298942080 doi "https://doi.org/10.1002/cphc.201600073" @default.
• W2298942080 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26972801" @default.
• W2298942080 hasPublicationYear "2016" @default.
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