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- W2299630588 abstract "Abstract Plutonium (V) in oxalate solutions in the pH region 2 to 5·5 has been found to be unstable to disproportionation giving rise to plutonium(VI) and plutonium(IV). The rate of disproportionation is proportional to the second power of the plutonium(V) concentration and decreases with decreasing hydrogen ion concentration. The dependence of the rate and extent of disproportionation on pH, oxalate concentration and plutonium concentration has been studied. An activation energy of 10·0 kcal/mole has been computed from the temperature dependence of the second order rate constant for the disproportionation of plutonium (V) in 0·03 M oxalate solution at pH 2." @default.
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- W2299630588 date "1969-10-31" @default.
- W2299630588 modified "2023-09-26" @default.
- W2299630588 title "STUDIES ON THE DISPROPORTIONATION OF PLUTONIUM(V) IN OXALATE MEDIUM." @default.
- W2299630588 hasPublicationYear "1969" @default.
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