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- W2299684230 endingPage "1367" @default.
- W2299684230 startingPage "1362" @default.
- W2299684230 abstract "Abstract A nickel/NHC system for regioselective oxidative annulation by double C−H bond activation and concomitant alkyne insertion is described. The catalytic reaction requires a bidentate directing group, such as an 8‐aminoquinoline, embedded in the substrate. Various 5,6,7,8‐tetrasubstituted‐ N ‐(quinolin‐8‐yl)‐1‐naphthamides can be prepared as well as phenanthrene and benzo[h]quinoline amide derivatives. Diarylalkynes, dialkylalkynes, and arylalkylalkynes can be used in the system. A Ni 0 /Ni II catalytic cycle is proposed as the main catalytic cycle. The alkyne plays a double role as a two‐component coupling partner and as a hydrogen acceptor." @default.
- W2299684230 created "2016-06-24" @default.
- W2299684230 creator A5013108842 @default.
- W2299684230 creator A5023225667 @default.
- W2299684230 creator A5025351157 @default.
- W2299684230 creator A5049915510 @default.
- W2299684230 date "2015-12-21" @default.
- W2299684230 modified "2023-10-12" @default.
- W2299684230 title "Chelation‐Assisted Nickel‐Catalyzed Oxidative Annulation via Double C−H Activation/Alkyne Insertion Reaction" @default.
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- W2299684230 doi "https://doi.org/10.1002/chem.201504596" @default.
- W2299684230 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26689750" @default.
- W2299684230 hasPublicationYear "2015" @default.
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