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- W2300129229 abstract "Relying on the nucleophilicity of silanol for building up silicon-incorporated scaffold with an enantiopure tetrasubstituted carbon center remains elusive. In this report, asymmetric bromo-oxycyclization of olefinic silanol by using chiral anionic phase-transfer catalyst is described. This protocol provided a facile entry to a wide arrangement of enantiopure benzoxasilole in moderate to excellent enantioselectivities depending on the unique reactivity of bromine/N-benzyl-DABCO complex." @default.
- W2300129229 created "2016-06-24" @default.
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- W2300129229 date "2015-12-14" @default.
- W2300129229 modified "2023-10-12" @default.
- W2300129229 title "Enantioselective Bromo-oxycyclization of Silanol" @default.
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- W2300129229 doi "https://doi.org/10.1021/acs.orglett.5b03303" @default.
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