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- W2300555794 abstract "The quenching of electronically excited bromine atoms Br(4 /sup 2/P/sub 1///sub 2/) upon collision with H/sub 2/, HD, and D/sub 2/ has been studied at 300 degreeK. The temporal profile of the Br(4 /sup 2/P/sub 1///sub 2/) concentration was monitored by observation of the time-resolved attenuation of bromine resonance radiation at 153.2 nm. The probabilities of deactivation by the hydrogen isotopes are presented and compared to theoretical treatments based either upon long-range coupling via mulitpolar interactions or explicit treatment of the nonadiabatic crossing probabilities computed using semiempirical potential surfaces. These results are then examined with a view toward assessing the importance of near-resonant electronic--vibrational energy transfer in such an elementary system. (AIP)" @default.
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- W2300555794 date "1976-08-15" @default.
- W2300555794 modified "2023-09-27" @default.
- W2300555794 title "Collisional deactivation of Br(4 /sup 2/P/sub 1///sub 2/) by hydrogen isotopes" @default.
- W2300555794 hasPublicationYear "1976" @default.
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