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• W2300768972 abstract "Light-switchable azoimidazoles were rationally designed and synthesized, and their performance was investigated as photodissociable ligands (PDL) and for spin state switching of Ni porphyrins. The rationally designed ligands exhibit a high photochemical conversion rate (trans → cis > 98%) and no measurable fatigue over a large number of switching cycles at room temperature under air. As compared to the known phenylazopyridines, the phenylazoimidazoles exhibit a much stronger affinity as axial ligands to Ni porphyrin in the binding trans configuration and a low affinity in their cis form. This affinity switching was used to control the coordination number of Ni2+. Concomitant with the change in coordination number is the change of the spin state from triplet (high spin) to singlet state (low spin). We report on phenylazoimidazole-based PDLs that switch the paramagnetic ratio of the investigated nickel species by up to 70%. Consequently, azoimidazoles exhibit considerably higher switching efficiencies than previously described pyridine-based PDLs." @default.
• W2300768972 created "2016-06-24" @default.
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• W2300768972 date "2016-01-27" @default.
• W2300768972 modified "2023-10-03" @default.
• W2300768972 title "Design and Synthesis of Photodissociable Ligands Based on Azoimidazoles for Light-Driven Coordination-Induced Spin State Switching in Homogeneous Solution" @default.
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• W2300768972 doi "https://doi.org/10.1021/acs.joc.5b02817" @default.
• W2300768972 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26761623" @default.
• W2300768972 hasPublicationYear "2016" @default.
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