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- W2300905903 abstract "Magnetic Fe3O4–polydopamine (PDA) hybrid hollow microspheres, in which Fe3O4 nanoparticles were firmly incorporated in the cross-linked PDA shell, have been prepared through the formation of core/shell PS/Fe3O4–PDA composites based on template-induced covalent assembly method, followed by core removal in a tetrahydrofuran solution. The morphology, composition, thermal property and magnetic property of the magnetic hybrid hollow microspheres were characterized by SEM, TEM, FT-IR, XRD, TGA, and vibrating sample magnetometer, respectively. Results revealed that the magnetic hybrid hollow microspheres had about 380 nm of inner diameter and about 30 nm of shell thickness, and 13.6 emu g−1 of magnetization saturation. More importantly, the Fe3O4–PDA hybrid hollow microspheres exhibited intrinsic peroxidase-like activity, as they could quickly catalyze the oxidation of typical substrates 3,3′,5,5′-tetramethylbenzidine (TMB) in the presence of hydrogen peroxide. Compared with PDA/Fe3O4 composites where Fe3O4 nanoparticles were loaded on the surface of PDA microspheres, the stability of Fe3O4–PDA hybrid hollow microspheres was greatly improved. As-prepared magnetic hollow microspheres might open up a new application field in biodetection, biocatalysis, and environmental monitoring." @default.
- W2300905903 created "2016-06-24" @default.
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- W2300905903 date "2016-05-01" @default.
- W2300905903 modified "2023-10-02" @default.
- W2300905903 title "Magnetically separable and recyclable Fe3O4–polydopamine hybrid hollow microsphere for highly efficient peroxidase mimetic catalysts" @default.
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- W2300905903 doi "https://doi.org/10.1016/j.jcis.2016.02.011" @default.
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