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- W2300967877 abstract "The authors have shown that the complex (Rh(PPh/sub 3/)/sub 2/SnCl/sub 3/) (I) is an active catalyst for the isomerization of 1-hexene to a mixture of cis- and trans-2-hexenes and cis- and trans-3-hexenes in CH/sub 2/Cl/sub 2/ at 25/sup 0/C in the absence of molecular hydrogen. The addition of gaseous HCl or excess PPh/sub 3/ sharply lowers the catalyst activity. The observed reaction presumably proceeds through a ..pi..-allylhydride mechanism (i.e., though the ((eta/sup 3/-allyl)RhH(PPh/sub 3/)/sub 2/SnCl/sub 3/) intermediate). This is indicated by 1,3 deuterium migration leading to a random deuterium distribution between C/sup 1/ and C/sup 3/ in 3-propene-D/sub 1/ upon its reaction with (I) in CH/sub 2/Cl/sub 2/ studied using /sup 13/C NMR spectroscopy." @default.
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- W2300967877 date "1986-06-20" @default.
- W2300967877 modified "2023-09-27" @default.
- W2300967877 title "Isomerization of alkenes catalyzed by (Rh(PPh/sub 3/)/sub 3/SnCl/sub 3/)" @default.
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