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• W2301436513 abstract "A scalable growth process for domain engineered {001}‐oriented lead magnesium niobate—lead titanate (PMN‐PT) thin films with Lotgering factors of 0.98–1.0, without an orienting perovskite seed layer, is presented. Deposition of a 2–3‐nm‐thick PbO buffer layer on {111} Pt thin film bottom electrodes, prior to chemical solution deposition of PMN‐PT reduces the driving force for Pb diffusion from the PMN‐PT to the bottom electrode, and facilitates nucleation of {001}‐oriented perovskite grains. Energy dispersive spectroscopy demonstrated that up to 10% of the Pb from a PMN‐PT precursor solution may diffuse into the bottom electrode. PMN‐PT grains with a mixed {101}/{111} orientation in a matrix of Pb‐deficient pyrochlore phase were then promoted near the interface. When this is prevented, phase‐pure films with {001} orientation can be achieved." @default.
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• W2301436513 date "2016-03-02" @default.
• W2301436513 modified "2023-10-18" @default.
• W2301436513 title "Management of Lead Content for Growth of {001}-Oriented Lead Magnesium Niobate-Lead Titanate Thin Films" @default.
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• W2301436513 doi "https://doi.org/10.1111/jace.14191" @default.
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