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• W2301479480 abstract "Two new lanthanide(III) complexes were designed and synthesized: DAS[M(TTA)4]–, (M = Sm [1], M = Eu [2]), each of them contained one trans-4-[4′-(N, N-dimethylamino)styryl]-N-methyl pyridinium (DAS) cationic moiety, four 2-thenoyltrifluoroacetone anions (TTA-), and one cationic lanthanide(III). Herein, the structures were confirmed by single-crystal X-ray diffraction analysis. The results revealed that the central lanthanide(III) atom was fashionable eight-coordinated with square-antiprismatic coordination environment. Meanwhile, the photophysical properties of 1 and 2 were investigated by fluorescence spectra. It was proposed that there was an antenna effect and the energy transfer took place from the DAS cationic moiety to lanthanide(III) ions." @default.
• W2301479480 created "2016-06-24" @default.
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• W2301479480 date "2016-03-02" @default.
• W2301479480 modified "2023-09-26" @default.
• W2301479480 title "Synthesis, Crystal Structures, and Photophysical Properties Investigations of Two New Pyridinium Complexes Containing [Sm(TTA)4]– and [Eu(TTA)4]–" @default.
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• W2301479480 doi "https://doi.org/10.1080/15533174.2015.1004427" @default.
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