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• W2301480358 abstract "A synthetic methodology is developed to generate boron rich aromatic small molecules based on benzene and pyrene moieties for the detection of thermal neutrons. The prepared aromatic compounds have a relatively high boron content up to 7.4 wt%, which is important for application in neutron detection as (10)B (20% of natural abundance boron) has a large neutron induced reaction cross-section. This is demonstrated by preparing blends of the synthesized molecules with fluorescent dopants in poly(vinyltoluene) matrices resulting in comparable scintillation light output and neutron capture as state-of-the art commercial scintillators, but with the advantage of much lower cost. The boron-rich benzene and pyrene derivatives are prepared by Suzuki conditions using both microwave and traditional heating, affording yields of 40-93%. This new procedure is simple and straightforward, and has the potential to be scaled up." @default.
• W2301480358 created "2016-06-24" @default.
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• W2301480358 date "2015-09-03" @default.
• W2301480358 modified "2023-10-16" @default.
• W2301480358 title "Boron-rich benzene and pyrene derivatives for the detection of thermal neutrons" @default.
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• W2301480358 doi "https://doi.org/10.1038/srep13401" @default.
• W2301480358 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4558605" @default.
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