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- W2304771975 abstract "Single crystals of the title compound, [Co(C(6)H(4)NO(2))(C(18)H(27)N(6)P)]NO(3), were obtained from the reaction of nitrato[tris-(2-isopropyl-imidazol-4-yl)phosphane]cobalt(II) nitrate with picolinic acid in the presence of potassium tert-butoxide as base. The coordination polyhedron around the central Co(II) ion is about halfway between square-pyramidal and trigonal-bipyramidal geometry. In the structure, the nitrate counter-anion is connected by N-H⋯O hydrogen bonding to the complex cation. Additionally, the complex cations form one-dimensional chains along [010] by hydrogen bonding of the NH group of an imidazole ring to the picolinate group of a neighbouring complex cation." @default.
- W2304771975 created "2016-06-24" @default.
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- W2304771975 date "2012-02-10" @default.
- W2304771975 modified "2023-09-26" @default.
- W2304771975 title "(Picolinato-κ<sup>2</sup><i>N</i>,<i>O</i>)[tris(2-isopropyl-1<i>H</i>-imidazol-4-yl-κ<i>N</i><sup>3</sup>)phosphane]cobalt(II) nitrate" @default.
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- W2304771975 doi "https://doi.org/10.1107/s1600536812004485" @default.
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