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- W2305843648 startingPage "4832" @default.
- W2305843648 abstract "The reaction of oxorhenium complexes that incorporate diamidopyridine (DAP) ligands with B(C6F5)3 results in the formation of classical Lewis acid-base adducts. The adducts effectively catalyze the hydrogenation of a variety of unactivated olefins at 100 °C. Control reactions with these complexes or B(C6F5)3 alone did not yield any hydrogenated products under these conditions. Mechanistic studies suggest a frustrated Lewis pair is generated between the oxorhenium DAP complexes and B(C6F5)3, which is effective at olefin hydrogenation. Thus, we demonstrate for the first time that the incorporation of a transition-metal oxo in a frustrated Lewis pair can have a synergistic effect and results in enhanced catalytic activity." @default.
- W2305843648 created "2016-06-24" @default.
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- W2305843648 date "2016-04-05" @default.
- W2305843648 modified "2023-10-01" @default.
- W2305843648 title "Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs" @default.
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- W2305843648 doi "https://doi.org/10.1021/jacs.6b00705" @default.
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