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- W2306561005 abstract "The title compound bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridobismuthate(III)] dihydrate, (C 6 H 14 N 2 ) 2 [Bi 2 Cl 10 ]·2H 2 O, was obtained by slow evaporation at room temperature of a hydrochloric aqueous solution (pH = 1) containing bismuth(III) nitrate and 1,4-diazabicyclo[2.2.2]octane (DABCO) in a 1:2 molar ratio. The structure displays a two-dimensional arrangement parallel to (100) of isolated [Bi 2 Cl 10 ] 4− bioctahedra (site symmetry -1) separated by layers of organic 1,4-diazoniabicyclo[2.2.2]octane dications [(DABCOH 2 ) 2+ ] and water molecules. O—H...Cl, N—H...O and N—H...Cl hydrogen bonds lead to additional cohesion of the structure." @default.
- W2306561005 created "2016-06-24" @default.
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- W2306561005 date "2015-10-28" @default.
- W2306561005 modified "2023-09-26" @default.
- W2306561005 title "Crystal structure of the new hybrid material bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridobismuthate(III)] dihydrate" @default.
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- W2306561005 doi "https://doi.org/10.1107/s2056989015019933" @default.
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