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- W2306768524 abstract "One of the main tasks of electrochemical impedance spectroscopy (EIS) is a synthesis of the equivalent electrical circuit based on experimental data in the broad range of frequencies. This problem, in principle, should be solved without recourse to a priori model of the impedance of the electrode process. In electrical engineering, the synthesis problem is solved by means of representing the impedance either using Cauer canonical forms [1] or Foster canonical forms [2]. In electrochemistry, the forms of Foster are more commonly used for the synthesis of an equivalent electrical circuit. According to the first Foster form, the impedance of the electrochemical system is represented as a series connection of several elements that constitute the parallel connection of resistor and capacitor [2]. For the second Foster form, the admittance of the system is given as a parallel connection of several elements that include a series connection of resistor and capacitor. Both forms are the result of the expansion of the function of the input resistance (conductance) of the circuit to a sum of single fractions. Denominators of these fractions are the roots of the numerator and denominator of the rational fraction with respect to ω j . In electrochemistry, there are models of admittances of electrochemical systems whose input functions include polynomials with respect to ( ) 2 / 1 ω j . For example, the admittance of hydrogen evolution, when the part of the adsorbed hydrogen atoms diffuses along the surface to the reaction center, where formation of molecular hydrogen takes place (equation 7 in [3]) has the following form:" @default.
- W2306768524 created "2016-06-24" @default.
- W2306768524 date "2011-01-01" @default.
- W2306768524 modified "2023-09-25" @default.
- W2306768524 title "Synthesis of Equivalent Electrical Circuits Based on Electrochemical Impedance Data" @default.
- W2306768524 doi "https://doi.org/10.1149/ma2011-02/46/2627" @default.
- W2306768524 hasPublicationYear "2011" @default.
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