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- W2307231714 abstract "We developed a facile and practical synthesis of N-Boc-aminals, which can be used as precursors for less accessible N-Boc-imines. Aminals were obtained via simple dehydration condensation reactions of t-butyl carbamate (BocNH2) and various aldehydes in acetic anhydride, followed by filtration and washing with hexane. The obtained N-Boc-alkynylaminals could be successfully applied in enantioselective Mannich-type reactions, catalyzed by chiral phosphoric acids, to afford optically active propargylamine derivatives." @default.
- W2307231714 created "2016-06-24" @default.
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- W2307231714 date "2016-06-01" @default.
- W2307231714 modified "2023-09-27" @default.
- W2307231714 title "N-Boc-aminals as easily accessible precursors for less accessible N-Boc-imines: facile synthesis of optically active propargylamine derivatives using Mannich-type reactions" @default.
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- W2307231714 doi "https://doi.org/10.1016/j.tet.2016.03.076" @default.
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