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• W2307661708 endingPage "71" @default.
• W2307661708 startingPage "67" @default.
• W2307661708 abstract "Tetra coordinated copper(II) complex of formula [Cu(L1)(imid)] is synthesized using imidazole and a tridentate O,N,O hydrazone ligand L1 prepared by condensation of 1,1,1-trifluoropentanedione and 4-chlorobenzhydrazide. The ligand and complex are characterized by UV–Visible, FTIR, NMR, mass and single crystal XRD techniques. DNA binding mode is assessed by UV absorption, fluorescence spectral and circular dichroism studies. Based on the results, it is observed that complex has preferred intercalative mode of binding with DNA. The binding constant, Kb, was found to be 4.02 ± 0.09 × 104 M− 1. Thermodynamic parameters such as ΔH, ΔS and ΔG obtained from acridine orange fluorescence displacement assay revealed that the hydrophobic and hydrogen bonding interactions are playing a major role in the binding pattern. In addition, cytotoxicity of the complex towards MCF-7 breast cancer cell line has also been assessed." @default.
• W2307661708 created "2016-06-24" @default.
• W2307661708 creator A5042886215 @default.
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• W2307661708 date "2016-05-01" @default.
• W2307661708 modified "2023-09-26" @default.
• W2307661708 title "DNA interaction and cytotoxic activity of copper complex based on tridentate hydrazone derived ligand and nitrogen donor heterocycle" @default.
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• W2307661708 doi "https://doi.org/10.1016/j.inoche.2016.03.012" @default.
• W2307661708 hasPublicationYear "2016" @default.
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