Matches in SemOpenAlex for { <https://semopenalex.org/work/W2307881598> ?p ?o ?g. }
- W2307881598 endingPage "72" @default.
- W2307881598 startingPage "66" @default.
- W2307881598 abstract "Methoxychlor [or 4,4′-(2,2,2-trichloroethane-1,1-diyl)bis(methoxybenzene)], a common environmental pollutant, has been catalytically reduced with nickel(I) salen electrogenerated in situ at carbon cathodes in dimethylformamide (DMF) containing 0.050 M tetra-n-butylammonium tetrafluoroborate (TBABF4). Cyclic voltammograms for reduction of nickel(II) salen in the presence of various concentrations of methoxychlor provide evidence for catalytic reduction. Cathodic peak currents for the nickel(II) salen–nickel(I) salen redox couple increase in proportion to the concentration of methoxychlor, whereas the anodic peak current associated with reoxidation of nickel(I) salen diminishes; in addition, a cathodic prepeak appears at higher concentrations of methoxychlor. Controlled-potential (bulk) electrolyses of nickel(II) salen at reticulated vitreous carbon cathodes in the presence of methoxychlor allowed the n value for reduction of methoxychlor to be determined. With the aid of gas chromatography–mass spectrometry, major electrolysis products have been identified as 4,4′-(2-chloroethene-1,1-diyl)bis(methoxybenzene) and 4,4′-(ethene-1,1-diyl)bis(methoxybenzene), and the product distribution was determined by means of gas chromatography. Adducts arising from the combination of fragments derived from methoxychlor and DMF have also been detected and confirmed, and a mechanistic scheme is proposed to account for the various products." @default.
- W2307881598 created "2016-06-24" @default.
- W2307881598 creator A5040963066 @default.
- W2307881598 creator A5045289003 @default.
- W2307881598 creator A5070832602 @default.
- W2307881598 creator A5083412956 @default.
- W2307881598 date "2016-07-01" @default.
- W2307881598 modified "2023-10-16" @default.
- W2307881598 title "Catalytic reduction of 4,4′-(2,2,2-trichloroethane-1,1-diyl)bis(methoxybenzene) (methoxychlor) with nickel(I) salen electrogenerated at reticulated vitreous carbon cathodes" @default.
- W2307881598 cites W1577776837 @default.
- W2307881598 cites W1837950453 @default.
- W2307881598 cites W1885876067 @default.
- W2307881598 cites W1966166880 @default.
- W2307881598 cites W1969560937 @default.
- W2307881598 cites W1980924600 @default.
- W2307881598 cites W1985436415 @default.
- W2307881598 cites W1996893833 @default.
- W2307881598 cites W1997066904 @default.
- W2307881598 cites W1999728297 @default.
- W2307881598 cites W2011087773 @default.
- W2307881598 cites W2014067175 @default.
- W2307881598 cites W2018961629 @default.
- W2307881598 cites W2032029034 @default.
- W2307881598 cites W2032376378 @default.
- W2307881598 cites W2032383901 @default.
- W2307881598 cites W2037212177 @default.
- W2307881598 cites W2038303272 @default.
- W2307881598 cites W2039874478 @default.
- W2307881598 cites W2051718247 @default.
- W2307881598 cites W2052948427 @default.
- W2307881598 cites W2064237951 @default.
- W2307881598 cites W2065118602 @default.
- W2307881598 cites W2066118909 @default.
- W2307881598 cites W2068750325 @default.
- W2307881598 cites W2074140475 @default.
- W2307881598 cites W2074515123 @default.
- W2307881598 cites W2080783278 @default.
- W2307881598 cites W2084869994 @default.
- W2307881598 cites W2086399903 @default.
- W2307881598 cites W2087263140 @default.
- W2307881598 cites W2091939163 @default.
- W2307881598 cites W2093802319 @default.
- W2307881598 cites W2096569879 @default.
- W2307881598 cites W2098718348 @default.
- W2307881598 cites W2106050349 @default.
- W2307881598 cites W2142359575 @default.
- W2307881598 cites W2171192677 @default.
- W2307881598 cites W2252839074 @default.
- W2307881598 cites W2318465671 @default.
- W2307881598 cites W2323202086 @default.
- W2307881598 cites W3004631326 @default.
- W2307881598 cites W1967795824 @default.
- W2307881598 doi "https://doi.org/10.1016/j.jelechem.2016.03.024" @default.
- W2307881598 hasPublicationYear "2016" @default.
- W2307881598 type Work @default.
- W2307881598 sameAs 2307881598 @default.
- W2307881598 citedByCount "10" @default.
- W2307881598 countsByYear W23078815982016 @default.
- W2307881598 countsByYear W23078815982017 @default.
- W2307881598 countsByYear W23078815982018 @default.
- W2307881598 countsByYear W23078815982020 @default.
- W2307881598 countsByYear W23078815982021 @default.
- W2307881598 countsByYear W23078815982022 @default.
- W2307881598 crossrefType "journal-article" @default.
- W2307881598 hasAuthorship W2307881598A5040963066 @default.
- W2307881598 hasAuthorship W2307881598A5045289003 @default.
- W2307881598 hasAuthorship W2307881598A5070832602 @default.
- W2307881598 hasAuthorship W2307881598A5083412956 @default.
- W2307881598 hasConcept C147789679 @default.
- W2307881598 hasConcept C161176658 @default.
- W2307881598 hasConcept C161790260 @default.
- W2307881598 hasConcept C17525397 @default.
- W2307881598 hasConcept C178790620 @default.
- W2307881598 hasConcept C179104552 @default.
- W2307881598 hasConcept C185592680 @default.
- W2307881598 hasConcept C2777869211 @default.
- W2307881598 hasConcept C2780509179 @default.
- W2307881598 hasConcept C31264372 @default.
- W2307881598 hasConcept C504270822 @default.
- W2307881598 hasConcept C52859227 @default.
- W2307881598 hasConcept C6557445 @default.
- W2307881598 hasConcept C86803240 @default.
- W2307881598 hasConceptScore W2307881598C147789679 @default.
- W2307881598 hasConceptScore W2307881598C161176658 @default.
- W2307881598 hasConceptScore W2307881598C161790260 @default.
- W2307881598 hasConceptScore W2307881598C17525397 @default.
- W2307881598 hasConceptScore W2307881598C178790620 @default.
- W2307881598 hasConceptScore W2307881598C179104552 @default.
- W2307881598 hasConceptScore W2307881598C185592680 @default.
- W2307881598 hasConceptScore W2307881598C2777869211 @default.
- W2307881598 hasConceptScore W2307881598C2780509179 @default.
- W2307881598 hasConceptScore W2307881598C31264372 @default.
- W2307881598 hasConceptScore W2307881598C504270822 @default.
- W2307881598 hasConceptScore W2307881598C52859227 @default.
- W2307881598 hasConceptScore W2307881598C6557445 @default.
- W2307881598 hasConceptScore W2307881598C86803240 @default.
- W2307881598 hasLocation W23078815981 @default.
- W2307881598 hasOpenAccess W2307881598 @default.