Matches in SemOpenAlex for { <https://semopenalex.org/work/W2308059765> ?p ?o ?g. }
- W2308059765 endingPage "248" @default.
- W2308059765 startingPage "237" @default.
- W2308059765 abstract "A nanodiamond-polymer composite monolithic column was first prepared successfully with modified nanodiamond (ND) as monomer, ethylene glycol dimethacrylate (EDMA) as cross-linker, 1-dodecanol as porogenic agent and benzoyl peroxide/dimethylacetamide (BPO/DMA) as initiator at 35 °C for 2.5 h. There was a sharp increase of specific surface area with ND added about 22 times from 0 mg (3.90 m2/g) to 7 mg (81.2 m2/g) determined with BET. Characterizations including scanning electron microscopy (SEM), fourier-transform infrared spectra (FIRT) and mercury intrusion porosimetry (MIP) were used to determine the microstructure, group composition, pore size distribution (≃1.56μm) and porosity (≃0.7484μm) of the monolith. An excellent column stability was confirmed by permeability (1.258x10−10cm2) and good linearity (R2=0.998) corresponding to backpressures measured at different flow rates. The highest swelling ability of the composite was about (5%) and classical RPLC of the column obtained occurred with the acetonitrile concentration increasing from 20% to 85% in the mobile phase, above which another retention model of normal-phase chromatography appeared. The items of the eddy dispersion and the absorption-release kinetics were the decisional factors of the composite column compared with the factors of longitudinal diffusion, and the skeleton-eluent mass transfer resistance due to the finite diffusivity. Good separation of neutral and basic small molecules was obtained (24,350 plates/m for neutral molecules and 22,300 plates/m for basic ones) with the hydrophobicity retention mechanism, but not for the acidic ones except to regulate the pH of the mobile phase." @default.
- W2308059765 created "2016-06-24" @default.
- W2308059765 creator A5001574275 @default.
- W2308059765 creator A5012137043 @default.
- W2308059765 creator A5027722055 @default.
- W2308059765 creator A5037824478 @default.
- W2308059765 creator A5041979975 @default.
- W2308059765 creator A5087210422 @default.
- W2308059765 date "2016-07-01" @default.
- W2308059765 modified "2023-10-14" @default.
- W2308059765 title "Property evaluations and application for separation of small molecules of a nanodiamond-polymer composite monolithic column" @default.
- W2308059765 cites W1190855270 @default.
- W2308059765 cites W1437649069 @default.
- W2308059765 cites W1888841404 @default.
- W2308059765 cites W1971640583 @default.
- W2308059765 cites W1978314075 @default.
- W2308059765 cites W1982045410 @default.
- W2308059765 cites W1982904970 @default.
- W2308059765 cites W1983403294 @default.
- W2308059765 cites W1988796421 @default.
- W2308059765 cites W1990069801 @default.
- W2308059765 cites W1994444676 @default.
- W2308059765 cites W1995813090 @default.
- W2308059765 cites W1996850043 @default.
- W2308059765 cites W2003060867 @default.
- W2308059765 cites W2003927235 @default.
- W2308059765 cites W2004539005 @default.
- W2308059765 cites W2005471568 @default.
- W2308059765 cites W2005860568 @default.
- W2308059765 cites W2009092357 @default.
- W2308059765 cites W2013880049 @default.
- W2308059765 cites W2021366306 @default.
- W2308059765 cites W2022135839 @default.
- W2308059765 cites W2037565909 @default.
- W2308059765 cites W2053957791 @default.
- W2308059765 cites W2056403962 @default.
- W2308059765 cites W2056535653 @default.
- W2308059765 cites W2060434199 @default.
- W2308059765 cites W2063621955 @default.
- W2308059765 cites W2065872257 @default.
- W2308059765 cites W2069094067 @default.
- W2308059765 cites W2069448160 @default.
- W2308059765 cites W2076602036 @default.
- W2308059765 cites W2077848804 @default.
- W2308059765 cites W2085093758 @default.
- W2308059765 cites W2086547981 @default.
- W2308059765 cites W2093269930 @default.
- W2308059765 cites W2112761851 @default.
- W2308059765 cites W2134778070 @default.
- W2308059765 cites W2141764164 @default.
- W2308059765 cites W2153354792 @default.
- W2308059765 cites W2162209826 @default.
- W2308059765 cites W2312237903 @default.
- W2308059765 cites W2316249668 @default.
- W2308059765 cites W2322261904 @default.
- W2308059765 cites W4235676315 @default.
- W2308059765 cites W982397404 @default.
- W2308059765 doi "https://doi.org/10.1016/j.talanta.2016.03.069" @default.
- W2308059765 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27154670" @default.
- W2308059765 hasPublicationYear "2016" @default.
- W2308059765 type Work @default.
- W2308059765 sameAs 2308059765 @default.
- W2308059765 citedByCount "8" @default.
- W2308059765 countsByYear W23080597652017 @default.
- W2308059765 countsByYear W23080597652018 @default.
- W2308059765 countsByYear W23080597652019 @default.
- W2308059765 countsByYear W23080597652021 @default.
- W2308059765 countsByYear W23080597652022 @default.
- W2308059765 crossrefType "journal-article" @default.
- W2308059765 hasAuthorship W2308059765A5001574275 @default.
- W2308059765 hasAuthorship W2308059765A5012137043 @default.
- W2308059765 hasAuthorship W2308059765A5027722055 @default.
- W2308059765 hasAuthorship W2308059765A5037824478 @default.
- W2308059765 hasAuthorship W2308059765A5041979975 @default.
- W2308059765 hasAuthorship W2308059765A5087210422 @default.
- W2308059765 hasConcept C104779481 @default.
- W2308059765 hasConcept C113196181 @default.
- W2308059765 hasConcept C127413603 @default.
- W2308059765 hasConcept C134871310 @default.
- W2308059765 hasConcept C152815550 @default.
- W2308059765 hasConcept C159985019 @default.
- W2308059765 hasConcept C160892712 @default.
- W2308059765 hasConcept C161790260 @default.
- W2308059765 hasConcept C166940927 @default.
- W2308059765 hasConcept C178790620 @default.
- W2308059765 hasConcept C179998833 @default.
- W2308059765 hasConcept C185592680 @default.
- W2308059765 hasConcept C192562407 @default.
- W2308059765 hasConcept C2775968528 @default.
- W2308059765 hasConcept C2779794448 @default.
- W2308059765 hasConcept C42360764 @default.
- W2308059765 hasConcept C43617362 @default.
- W2308059765 hasConcept C51724486 @default.
- W2308059765 hasConcept C521977710 @default.
- W2308059765 hasConceptScore W2308059765C104779481 @default.
- W2308059765 hasConceptScore W2308059765C113196181 @default.
- W2308059765 hasConceptScore W2308059765C127413603 @default.
- W2308059765 hasConceptScore W2308059765C134871310 @default.