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- W2308333184 abstract "The hydrothermal crystallization of amorphous titanium dioxide at 300-600'C, I kbar pressure, follows the reaction path: amorphous reactant - anatase - rutile. The transformation is accelerated by increasing temperature and decreasing solution pH. Two mechanism stages can be envisaged: (1) the formation of anatase by the dehydration and gradual structural rearrangement of the reactant titanium-oxygen lattice, and (2) solution of the anatase intermediate and direct precipitation of rutile. The metastable development of anatase is in accordance with a modern formulation of the Ostwald Step Rule." @default.
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- W2308333184 date "1976-01-01" @default.
- W2308333184 modified "2023-09-26" @default.
- W2308333184 title "The crystallization of anatase and rutile from amorphous titanium dioxide under hydrothermal conditions" @default.
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