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• W2308363554 abstract "Abstract The phase equilibria in the system Ag–Pd–Te were studied by the technique of using an evacuated silica glass tube at 350° and 450°C. Five ternary phases were synthesized: sopcheite (Pd 3 Ag 4 Te 4 ), lukkulaisvaaraite (Pd 14 Ag 2 Te 9 ),telargpalite (Pd 2– x Ag 1+ x Te) and the previously unknown phases Pd 7.5– x Ag 0.5+ x Te 3 and Pd 2+ x Ag 2– x Te.The synthetic telargpalite has a compositional range from 26 to 29 wt.% Ag, with the formula Pd 2–x Ag 1+ x Te, where x varies from 0.09 to 0.22. The phase Pd 2+ x Ag 2– x Te has a compositional range from 34 to 35 wt.% Ag, where x varies from 0.18 to 0.24. The phase Pd 7.5– x Ag 0.5+ x Te 3 forms a solid solution from 4 to 11 wt.% Ag, where x varies from 0.02 to 0.83. Phases Pd 20 Te 7 and Pd 13 Te 3 dissolve up to 3.5 and 2 wt.% Ag, respectively. Other binary palladium tellurides do not dissolve Ag. The phase Pd 3 Ag 4 Te 4 , an analogue of the mineral sopcheite, forms a stable association with hessite and kotulskite it also coexists with lukkulaisvaaraite. Sopcheite is stable up to 383°C. Natural occurrences of hessite, kotulskite and lukkulaisvaaraite together in equilibrium indicate formation above this temperature. Phase relations defined the mineral assemblages that can be expected to occur in nature.The phase Pd 7.5– x Ag 0.5+ x Te 3 potentially represents a new mineral; it will probably be found in association with lukkulaisvaaraite and telargpalite or telluropalladinite, among other platinum-group minerals. The phasePd 2+ x Ag 2– x Te can be found in association with telargpalite. Mineral assemblages defined in this study can be expected in Cu-Ni-PGE mineral deposits, associated with mafic and ultramafic igneous rocks, particularly in mineralized zones with known silver-palladium tellurides." @default.
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• W2308363554 date "2015-12-01" @default.
• W2308363554 modified "2023-10-03" @default.
• W2308363554 title "The system Ag–Pd–Te: phase relations and mineral assemblages" @default.
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• W2308363554 doi "https://doi.org/10.1180/minmag.2015.079.7.11" @default.
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