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- W2308468525 abstract "Chitin, the most abundant nitrogen-containing biopolymer, includes both glycosidic bonds and N-acetyl groups in its structure and is an attractive source of useful monomers such as N-acetylglucosamine (GlcNAc) and 1-O-methyl-N-acetylglucosamine (MeGlcNAc). In order to synthesize the N-acetylated monomers in high yields, selective hydrolysis of glycosidic bonds in chitin without deacetylation is absolutely necessary. In this chapter, new two-step catalytic depolymerization of chitin to the N-acetylated monomers has been developed: (i) mechanical force-assisted hydrolysis of chitin to water-soluble oligomers and (ii) thermocatalytic solvolysis, hydrolysis, and methanolysis in this study, of the oligomers to the N-acetylated monomers. In both steps, deacetylation does not happen, resulting in good yields of GlcNAc (53 %) and MeGlcNAc (70 %)." @default.
- W2308468525 created "2016-06-24" @default.
- W2308468525 creator A5001517975 @default.
- W2308468525 date "2016-01-01" @default.
- W2308468525 modified "2023-10-01" @default.
- W2308468525 title "Catalytic Depolymerization of Chitin to N-Acetylated Monomers" @default.
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- W2308468525 doi "https://doi.org/10.1007/978-981-10-0332-5_4" @default.
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