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- W2308583976 abstract "Hexasubstituted benzenes have been synthesized with the highest known dipole moments, as determined by dielectric spectroscopy and DFT methods. Based on the preparation of 4,5-diamino-3,6-dibromophthalonitrile, combined with a novel method to synthesize dihydrobenzimidazoles, these benzene derivatives have dipole moments in excess of 10 debye. Such dipole moments are desirable in ferroelectrics, nonlinear optics, and in organic photovoltaics. Structure determination was achieved through single-crystal X-ray crystallography, and the optical properties were determined by UV/Vis absorption and fluorescence spectroscopy." @default.
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- W2308583976 date "2016-02-02" @default.
- W2308583976 modified "2023-10-18" @default.
- W2308583976 title "Hexasubstituted Benzenes with Ultrastrong Dipole Moments" @default.
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- W2308583976 doi "https://doi.org/10.1002/anie.201508249" @default.
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