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- W2309006469 abstract "In the development of proton exchange membrane fuel cells (PEMFCs), the cost of balance of plant (BOP) materials and their effect on PEMFC durability can retard commercialization. One opportunity to decrease these costs would be to use off-the-shelf materials rather than custommade materials if leachates from the less expensive materials do not affect performance and lifetime. To understand contamination mechanisms and their impacts on PEMFCs, experimental studies conducted and found the sensitivity of performance to the low levels of contamination. A model for contamination of a PEMFC which includes adsorption on the Pt catalyst, absorption into the membrane, and ion-exchange with ionomeric components is presented. The model predictions for three sources of voltage (i.e., performance) loss account for two-dimensional timedependent contamination along the channel and into the membrane as shown in Figure 1. The model is developed by considering the well-known chemical engineering concepts of Langmuir adsorption, partition coefficients, plug flow reactors (PFRs), and dimensionless analysis. The phenomena are shown to be controlled by three important dimensionless groups: a Damhkoler number for the contamination reaction rate, a capacity ratio, and a coverage ratio for each contamination mechanism. Also, techniques are presented for translating the liquid phase thin film rotating disk electrode measurements of isotherms to the required in-situ parameters of the gas-phase model. For typical parameters, the predicted voltage loss in the electrode by an ion-exchange mechanism shows slower reaction rates but greater performance losses than other mechanisms. More broadly, the model also provides a tolerance limits for contamination. (a)" @default.
- W2309006469 created "2016-06-24" @default.
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- W2309006469 date "2013-01-01" @default.
- W2309006469 modified "2023-09-27" @default.
- W2309006469 title "An Isothermal Model for Predicting Performance Loss in Pemfcs From Bop Leachates" @default.
- W2309006469 doi "https://doi.org/10.1149/ma2013-02/15/1260" @default.
- W2309006469 hasPublicationYear "2013" @default.
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