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- W2309042246 endingPage "1563" @default.
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- W2309042246 abstract "The reactions of nido-2,4-(Cp*Co)2B3H7, 1, Cp* = (η5-C5Me5), with Fe2(CO)9 and Co2(CO)8 generate seven skeletal electron pair (sep) nido-1-{Cp*Co}-2-((CO)3Fe)B3H7, 2, by metal fragment substitution and seven sep arachno-Cp*(CO)CoB3H7, 3, by metal fragment degradation. Both compounds are characterized spectroscopically in solution and with single-crystal X-ray diffraction in the solid state. On the basis of the results and related chemistry, the suggested reaction pathway involves M(CO)4, M = Fe and Co, coordination to a Co−H−B edge of 1 followed by loss of Cp*Co(CO) which leads to 2. We postulate that the cobalt analogue of 2, which would be an odd-electron species, readily loses a cobalt carbonyl fragment to form 3." @default.
- W2309042246 created "2016-06-24" @default.
- W2309042246 creator A5018115355 @default.
- W2309042246 creator A5020188195 @default.
- W2309042246 creator A5029918281 @default.
- W2309042246 date "1998-03-24" @default.
- W2309042246 modified "2023-10-02" @default.
- W2309042246 title "Reactions of the Cobaltaborane 2,4-{(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Co}<sub>2</sub>B<sub>3</sub>H<sub>7</sub> with Metal Fragments. Synthesis and Characterization of <i>nido</i>-1-{(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Co}-2-{(CO)<sub>3</sub>Fe}B<sub>3</sub>H<sub>7</sub> and <i>arachno</i>-(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)(CO)CoB<sub>3</sub>H<sub>7</sub>" @default.
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- W2309042246 doi "https://doi.org/10.1021/om980010x" @default.
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