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- W2309200293 abstract "AssrRAcr The infrared sllectra of dundasite, strontiodresserite, dresserite, and hydrodresserite corroborate the occurrence of hydrogen bonding in the minerals. The hydroxyl groups are linked through H-bonds and tho frequency of hydroxyl stretching vibrations indicates that the hyfuogen bouds are of variable strength. The H-bond strengtl falls in the order: dundasite) strontiodresserite ) dresserite ) hydrodresserite. Hydrogen bonding to the carbonate groups produces bicarbonate-like spectral behavior in the minerals, Such behavior implies the structural formulae BaAlr0r(OH)s(HCOs)z.3HzO for hydrodresserite, and MN2O2(OH)2(HCO)r.HO for dundasite, dresserite, and strontiodresserite (M - pb, Ba. and Sr, respectively). Vibrational evidence also exists for the presence of hydrogen-bond linkages of metal-oxygen units. Structural water was detected in the minerals, but no definite evidence was found for water coordination through the formation of aquo complexes. The thermal decomposition of hydrodresserite produces a dresserite-like structurallv disordered intermediate compound. Definite vibritional similarities exist between dresserite and hvdrodresserite trom 22 to 275C; althougb compleie conversion of hydrodresserite to dresserite is not indicated by infrared vibrational analysis, X-ray diffraction studies do indicate such a transition." @default.
- W2309200293 created "2016-06-24" @default.
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- W2309200293 date "1977-08-01" @default.
- W2309200293 modified "2023-09-23" @default.
- W2309200293 title "Infrared investigation of basic double-carbonate hydrate minerals" @default.
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