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- W2309321969 abstract "The single pulse–pulsed laser polymerization–electron paramagnetic resonance (SP–PLP–EPR) method affords the detailed kinetic analysis of acrylamide polymerization in aqueous solution. Highly time-resolved SP–PLP–EPR experiments for 10 and 20 wt % AAm were first carried out at −5 °C, where only secondary propagating radicals (SPRs) occur. In a second step, the time evolution of midchain radicals (MCRs), produced from SPRs by backbiting, was measured at higher temperatures. The termination kinetics, including chain-length dependent termination of SPRs, the backbiting rate of SPRs, and the propagation rate of MCRs were determined. The rate coefficients from SP–PLP–EPR in conjunction with the known propagation rate coefficient of SPRs, enable the simulation of the kinetics and product properties of AAm radical polymerizations in aqueous solution." @default.
- W2309321969 created "2016-06-24" @default.
- W2309321969 creator A5014443257 @default.
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- W2309321969 date "2015-10-06" @default.
- W2309321969 modified "2023-10-16" @default.
- W2309321969 title "Termination and Transfer Kinetics of Acrylamide Homopolymerization in Aqueous Solution" @default.
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- W2309321969 doi "https://doi.org/10.1021/acs.macromol.5b01921" @default.
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