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- W2309618881 abstract "The methyl labelled C3-bridged frustrated phosphane borane Lewis pair (P/B FLP) 2 b was prepared by treatment of Mes2PCl with a methallyl Grignard reagent followed by anti-Markovnikov hydroboration with Piers’ borane [HB(C6F5)2)]. The FLP 2 b is inactive toward dihydrogen under typical ambient conditions, in contrast to the C2- and C4-bridged FLP analogues. Dynamic NMR spectroscopy showed that this was not due to kinetically hindered P⋅⋅⋅B dissociation of 2 b. DFT calculations showed that the hydrogen-splitting reaction of the parent compound 2 a is markedly endergonic. The PH+/BH− H2-splitting product of 2 b was indirectly synthesized by a sequence of H+/H− addition. It lost H2 at ambient conditions and confirmed the result of the DFT analysis." @default.
- W2309618881 created "2016-06-24" @default.
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- W2309618881 date "2016-03-21" @default.
- W2309618881 modified "2023-10-12" @default.
- W2309618881 title "Why Does the Intramolecular Trimethylene-Bridged Frustrated Lewis Pair Mes<sub>2</sub> PCH<sub>2</sub> CH<sub>2</sub> CH<sub>2</sub> B(C<sub>6</sub> F<sub>5</sub> )<sub>2</sub> Not Activate Dihydrogen?" @default.
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- W2309618881 doi "https://doi.org/10.1002/chem.201505200" @default.
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