Matches in SemOpenAlex for { <https://semopenalex.org/work/W2311883331> ?p ?o ?g. }
- W2311883331 endingPage "694" @default.
- W2311883331 startingPage "686" @default.
- W2311883331 abstract "The NO2 oxidation kinetics and burning mode for diesel particulate from light-duty and medium-duty engines fueled with either ultra low sulfur diesel or soy methyl ester biodiesel blends have been investigated and are shown to be significantly different from oxidation by O2. Oxidation kinetics were measured using a flow-through packed bed microreactor for temperature programmed reactions and isothermal differential pulsed oxidation reactions. The burning mode was evaluated using the same reactor system for flowing BET specific surface area measurements and HR-TEM with fringe analysis to evaluate the nanostructure of the nascent and partially oxidized particulates. The low activation energy measured, specific surface area progression with extent of oxidation, HR-TEM images and difference plots of fringe length and tortuosity paint a consistent picture of higher reactivity for NO2, which reacts indiscriminately immediately upon contact with the surface, leading to the Zone I or shrinking core type oxidation. In comparison, O2 oxidation is shown to have relatively lower reactivity, preferentially attacking highly curved lamella, which are more reactive due to bond strain, and short lamella, which have a higher proportion of more reactive edge sites. This preferential oxidation leads to Zone II type oxidation, where solid phase diffusion of oxygen via pores contributes significantly to slowing the overall oxidation rate, by comparison." @default.
- W2311883331 created "2016-06-24" @default.
- W2311883331 creator A5019885173 @default.
- W2311883331 creator A5065575512 @default.
- W2311883331 creator A5068680429 @default.
- W2311883331 creator A5090474577 @default.
- W2311883331 creator A5091297727 @default.
- W2311883331 date "2016-03-24" @default.
- W2311883331 modified "2023-09-26" @default.
- W2311883331 title "NO2 Oxidation Reactivity and Burning Mode of Diesel Particulates" @default.
- W2311883331 cites W1166488477 @default.
- W2311883331 cites W1528769890 @default.
- W2311883331 cites W1561817808 @default.
- W2311883331 cites W1578214040 @default.
- W2311883331 cites W1589406774 @default.
- W2311883331 cites W1600337329 @default.
- W2311883331 cites W1967834823 @default.
- W2311883331 cites W1972847216 @default.
- W2311883331 cites W2001565162 @default.
- W2311883331 cites W2007637154 @default.
- W2311883331 cites W2009147952 @default.
- W2311883331 cites W2011254969 @default.
- W2311883331 cites W2022366668 @default.
- W2311883331 cites W2026879032 @default.
- W2311883331 cites W2036568227 @default.
- W2311883331 cites W2044513520 @default.
- W2311883331 cites W2044775576 @default.
- W2311883331 cites W2044868967 @default.
- W2311883331 cites W2046189144 @default.
- W2311883331 cites W2047989828 @default.
- W2311883331 cites W2064192766 @default.
- W2311883331 cites W2068665529 @default.
- W2311883331 cites W2069695026 @default.
- W2311883331 cites W2071577885 @default.
- W2311883331 cites W2076061604 @default.
- W2311883331 cites W2085408152 @default.
- W2311883331 cites W2086302085 @default.
- W2311883331 cites W2095358084 @default.
- W2311883331 cites W2099720984 @default.
- W2311883331 cites W2117494848 @default.
- W2311883331 cites W2140932755 @default.
- W2311883331 cites W2174588215 @default.
- W2311883331 cites W2210697056 @default.
- W2311883331 cites W2225685479 @default.
- W2311883331 cites W2278157878 @default.
- W2311883331 cites W2318220216 @default.
- W2311883331 cites W2322071535 @default.
- W2311883331 cites W2323379596 @default.
- W2311883331 cites W2325442347 @default.
- W2311883331 cites W49412377 @default.
- W2311883331 cites W2037191527 @default.
- W2311883331 doi "https://doi.org/10.1007/s11244-016-0544-8" @default.
- W2311883331 hasPublicationYear "2016" @default.
- W2311883331 type Work @default.
- W2311883331 sameAs 2311883331 @default.
- W2311883331 citedByCount "21" @default.
- W2311883331 countsByYear W23118833312017 @default.
- W2311883331 countsByYear W23118833312018 @default.
- W2311883331 countsByYear W23118833312019 @default.
- W2311883331 countsByYear W23118833312020 @default.
- W2311883331 countsByYear W23118833312021 @default.
- W2311883331 countsByYear W23118833312022 @default.
- W2311883331 countsByYear W23118833312023 @default.
- W2311883331 crossrefType "journal-article" @default.
- W2311883331 hasAuthorship W2311883331A5019885173 @default.
- W2311883331 hasAuthorship W2311883331A5065575512 @default.
- W2311883331 hasAuthorship W2311883331A5068680429 @default.
- W2311883331 hasAuthorship W2311883331A5090474577 @default.
- W2311883331 hasAuthorship W2311883331A5091297727 @default.
- W2311883331 hasBestOaLocation W23118833312 @default.
- W2311883331 hasConcept C121332964 @default.
- W2311883331 hasConcept C127413603 @default.
- W2311883331 hasConcept C136301237 @default.
- W2311883331 hasConcept C142724271 @default.
- W2311883331 hasConcept C148898269 @default.
- W2311883331 hasConcept C159985019 @default.
- W2311883331 hasConcept C161790260 @default.
- W2311883331 hasConcept C178790620 @default.
- W2311883331 hasConcept C179104552 @default.
- W2311883331 hasConcept C185592680 @default.
- W2311883331 hasConcept C192562407 @default.
- W2311883331 hasConcept C204787440 @default.
- W2311883331 hasConcept C24245907 @default.
- W2311883331 hasConcept C2776910235 @default.
- W2311883331 hasConcept C42360764 @default.
- W2311883331 hasConcept C540031477 @default.
- W2311883331 hasConcept C55904794 @default.
- W2311883331 hasConcept C62520636 @default.
- W2311883331 hasConcept C69357855 @default.
- W2311883331 hasConcept C71924100 @default.
- W2311883331 hasConcept C78030364 @default.
- W2311883331 hasConcept C97355855 @default.
- W2311883331 hasConceptScore W2311883331C121332964 @default.
- W2311883331 hasConceptScore W2311883331C127413603 @default.
- W2311883331 hasConceptScore W2311883331C136301237 @default.
- W2311883331 hasConceptScore W2311883331C142724271 @default.
- W2311883331 hasConceptScore W2311883331C148898269 @default.
- W2311883331 hasConceptScore W2311883331C159985019 @default.