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• W2312174911 abstract "With the explosive development of analysis and detection techniques based on surface-enhanced Raman scattering (SERS), the further understanding and exploitation of the chemical mechanism becomes particularly important. We investigated the charge transfer (CT) effect on SERS in a semiconductor–molecule–metal system constructed with Ag NPs, 4-mercaptobenzoic acid (MBA) molecule, and atomic level TiO2. To ensure more ordering, the system is constructed by a layer-by-layer self-assembly method. After introducing TiO2, we found that the relative band intensity of some peaks displayed a distinct difference, which is attributed to the Herzberg–Teller contribution that occurs via CT. We also proposed a possible mechanism responsible for the selective enhancement observed in the SERS spectra of the Ag NPs/MBA/TiO2 system. This work will not only provide much deeper insight into the CT mechanism in SERS but also help in the development of a method to construct metal–semiconductor-based SERS substrates." @default.
• W2312174911 created "2016-06-24" @default.
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• W2312174911 date "2015-09-21" @default.
• W2312174911 modified "2023-10-17" @default.
• W2312174911 title "Charge-Transfer Effect on Surface-Enhanced Raman Scattering (SERS) in an Ordered Ag NPs/4-Mercaptobenzoic Acid/TiO₂ System" @default.
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• W2312174911 doi "https://doi.org/10.1021/acs.jpcc.5b06001" @default.
• W2312174911 hasPublicationYear "2015" @default.
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