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- W2312268045 abstract "Abstract Two optically active pseudo-hexopyranoses, pesudo-α-D-glucopyranose (1) and pseudo-β-L-altropyranose (2), were synthesized starting from L-arabinose. L-Arabinose was first converted to an acyclic aldehyde 9. The reaction of 9 with dimethyl malonate under basic conditions provided a tetra-hydroxylated cyclohexane-1,1-dicarboxylate 11 and a C-glycoside of β-L-arabinopyranose 12. From the compound 11, the desired two pseudo-sugars were synthesized by 1) thermal demethoxy-carbonylation, 2) LiAlH4, reduction, 3) hydroboration of the resulting 1-hydroxymethyl-l-cyclohexene 14 followed by hydrogen peroxide treatment, and 4) removal of the protecting groups." @default.
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- W2312268045 date "1987-05-01" @default.
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- W2312268045 title "Syntheses of Pseudo-α-<u>D</u>-Glucopyranose and Pseudo-β-<u>L</u>-Altropyranose From<u>L</u>-Arabinose" @default.
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- W2312268045 doi "https://doi.org/10.1080/07328308708058873" @default.
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