Matches in SemOpenAlex for { <https://semopenalex.org/work/W2312333021> ?p ?o ?g. }
- W2312333021 endingPage "17828" @default.
- W2312333021 startingPage "17821" @default.
- W2312333021 abstract "Inspired by the crucial role of nature hydrophobic regions in highly efficient enzymatic catalysis, this work proposes a simple but valid catalyst-design strategy by simply employing the interlayer region of layered double hydroxides (LDHs) to mimic the bilayer structure of nature phospholipids. The interlayer region of LDHs intercalated with dodecyl sulfonate, an amphiphilic species, provides bidimensional hydrophobic environments for encapsulated Mn(TPP)OAc. The Mn centers encapsulated in the hydrophobic interlayer region of LDHs has been found to exhibit superior catalytic activity to homogeneous counterpart in the epoxidation of a variety of alkenes, including cyclohexene, heptylene, phenylethylene, 3-methyl-3-buten-1-ol, and even functional alkenes such as ethyl cinnamate and chalcone. It has also been found that TOF increases with decreasing polarity of the catalyzed substrate while TON depends on the polarity difference between the catalyzed alkene and produced epoxide." @default.
- W2312333021 created "2016-06-24" @default.
- W2312333021 creator A5006924966 @default.
- W2312333021 creator A5047131675 @default.
- W2312333021 creator A5082515921 @default.
- W2312333021 creator A5083425407 @default.
- W2312333021 creator A5088450430 @default.
- W2312333021 date "2013-12-03" @default.
- W2312333021 modified "2023-09-22" @default.
- W2312333021 title "Enhanced Catalytic Efficiency in the Epoxidation of Alkenes for Manganese Complex Encapsulated in the Hydrophobic Interlayer Region of Layered Double Hydroxides" @default.
- W2312333021 cites W1971113556 @default.
- W2312333021 cites W1976277867 @default.
- W2312333021 cites W1977476622 @default.
- W2312333021 cites W1978416367 @default.
- W2312333021 cites W1979828122 @default.
- W2312333021 cites W1999771882 @default.
- W2312333021 cites W2009305817 @default.
- W2312333021 cites W2010007166 @default.
- W2312333021 cites W2011619162 @default.
- W2312333021 cites W2014764734 @default.
- W2312333021 cites W2016564597 @default.
- W2312333021 cites W2022650937 @default.
- W2312333021 cites W2023022880 @default.
- W2312333021 cites W2023978788 @default.
- W2312333021 cites W2034124957 @default.
- W2312333021 cites W2034961943 @default.
- W2312333021 cites W2037507880 @default.
- W2312333021 cites W2038225007 @default.
- W2312333021 cites W2040299058 @default.
- W2312333021 cites W2047572502 @default.
- W2312333021 cites W2050511094 @default.
- W2312333021 cites W2052850502 @default.
- W2312333021 cites W2055010055 @default.
- W2312333021 cites W2055761305 @default.
- W2312333021 cites W2055948489 @default.
- W2312333021 cites W2058241368 @default.
- W2312333021 cites W2062552733 @default.
- W2312333021 cites W2063766525 @default.
- W2312333021 cites W2065335146 @default.
- W2312333021 cites W2071021036 @default.
- W2312333021 cites W2075011339 @default.
- W2312333021 cites W2085104283 @default.
- W2312333021 cites W2090309596 @default.
- W2312333021 cites W2130945748 @default.
- W2312333021 cites W2138701720 @default.
- W2312333021 cites W2141230543 @default.
- W2312333021 cites W2155678338 @default.
- W2312333021 cites W2157253764 @default.
- W2312333021 cites W2169594520 @default.
- W2312333021 cites W2173048111 @default.
- W2312333021 cites W29013223 @default.
- W2312333021 cites W2949246524 @default.
- W2312333021 cites W2950338315 @default.
- W2312333021 cites W2950897647 @default.
- W2312333021 doi "https://doi.org/10.1021/ie4026693" @default.
- W2312333021 hasPublicationYear "2013" @default.
- W2312333021 type Work @default.
- W2312333021 sameAs 2312333021 @default.
- W2312333021 citedByCount "13" @default.
- W2312333021 countsByYear W23123330212014 @default.
- W2312333021 countsByYear W23123330212016 @default.
- W2312333021 countsByYear W23123330212017 @default.
- W2312333021 countsByYear W23123330212018 @default.
- W2312333021 countsByYear W23123330212019 @default.
- W2312333021 countsByYear W23123330212021 @default.
- W2312333021 crossrefType "journal-article" @default.
- W2312333021 hasAuthorship W2312333021A5006924966 @default.
- W2312333021 hasAuthorship W2312333021A5047131675 @default.
- W2312333021 hasAuthorship W2312333021A5082515921 @default.
- W2312333021 hasAuthorship W2312333021A5083425407 @default.
- W2312333021 hasAuthorship W2312333021A5088450430 @default.
- W2312333021 hasConcept C111368507 @default.
- W2312333021 hasConcept C121332964 @default.
- W2312333021 hasConcept C127313418 @default.
- W2312333021 hasConcept C15920480 @default.
- W2312333021 hasConcept C161790260 @default.
- W2312333021 hasConcept C178790620 @default.
- W2312333021 hasConcept C185592680 @default.
- W2312333021 hasConcept C192157962 @default.
- W2312333021 hasConcept C21951064 @default.
- W2312333021 hasConcept C2776254738 @default.
- W2312333021 hasConcept C2776920199 @default.
- W2312333021 hasConcept C2777289219 @default.
- W2312333021 hasConcept C2778002958 @default.
- W2312333021 hasConcept C2778894819 @default.
- W2312333021 hasConcept C2779484182 @default.
- W2312333021 hasConcept C41625074 @default.
- W2312333021 hasConcept C521977710 @default.
- W2312333021 hasConcept C528890316 @default.
- W2312333021 hasConcept C537181965 @default.
- W2312333021 hasConcept C55493867 @default.
- W2312333021 hasConcept C66882249 @default.
- W2312333021 hasConcept C67407626 @default.
- W2312333021 hasConcept C97355855 @default.
- W2312333021 hasConceptScore W2312333021C111368507 @default.
- W2312333021 hasConceptScore W2312333021C121332964 @default.
- W2312333021 hasConceptScore W2312333021C127313418 @default.
- W2312333021 hasConceptScore W2312333021C15920480 @default.